鍏夊MOF钖勮啘鏉愭枡鐮旂┒鑾峰緱紿佺牬鎬ц繘灞?/span>
2017-5-12 鏉ユ簮:紱忓緩鐗╄川緇撴瀯鐮旂┒鎵 鐐瑰嚮嬈?/span>
鍏抽敭璇嶏細MOF钖勮啘鏉愭枡
鏈榪戯紝涓浗縐戝闄㈢寤虹墿璐ㄧ粨鏋勭爺絀舵墍緇撴瀯鍖栧鍥藉閲嶇偣瀹為獙瀹ょ爺絀跺憳寮犲仴棰嗗鐨勭爺絀跺洟闃熸垚鍔熷悎鎴愪簡璐熻澆瓚呭皬紕崇撼綾崇偣闃電殑鍏夊MOF钖勮啘鏉愭枡銆?/span>
銆銆鍔熻兘澶嶅悎钖勮啘鏉愭枡鐨勯珮鏁堛佺粡嫻庡埗澶囨槸褰撳墠鏂板瀷钖勮啘鏉愭枡鐮斿彂鐨勯毦棰樹箣涓錛屽挨鍏舵槸鍏夊姛鑳藉鍚堣杽鑶滅殑鍒跺鍜屽簲鐢ㄨ繕闇瑕佸ぇ鍔涘彂灞曘?/span>
紕崇撼綾崇偣(CDs)鐢變簬鍏墮珮鍖栧紼沖畾鎬с佷綆姣掓с佽壇濂界殑鐢熺墿鍏煎鎬у拰浼樺紓鐨勫厜鐗╃悊鎬ц兘錛屽湪鍌寲銆佽崸鍏夈佷紶鎰熷拰鐢熺墿鎴愬儚絳夋柟闈㈤兘鏈夌潃騫挎硾鐨勫簲鐢ㄥ墠鏅傝鐮旂┒鍥㈤槦鍒涙柊鎬у湴鍒╃敤浜哅OF鏉愭枡鍜岃憽钀勭硸鍒嗗瓙鍦ㄧ⒊鍖栨俯搴︿笂鐨勬樉钁楀樊寮傦紝鍘誨疄鐜扮⒊綰崇背鐐逛笌MOF鏉愭枡鐨勫鍚堛備竴鑸琈OF鏉愭枡鐨勭⒊鍖栨俯搴﹂渶瓚呰繃500鎽勬皬搴︼紝鑰岃憽钀勭硸鍒嗗瓙鐨勭⒊鍖栨俯搴﹀嵈鍦?00鎽勬皬搴﹀乏鍙熾傚洜姝わ紝璐熻澆钁¤悇緋栧垎瀛愮殑MOF鏉愭枡鍦?00鎽勬皬搴︿笅淇濇寔楠ㄦ灦緇撴瀯涓嶅彉錛屼絾鏄憽钀勭硸琚⒊鍖栬涓洪檺鍒跺湪MOF瀛斾腑鐨勭⒊綰崇背鐐癸紝浠庤岃幏寰楀垎鏁ｅ潎涓鐨凜Ds@MOF澶嶅悎鏉愭枡銆?/span>
銆銆紕崇撼綾崇偣鐨勫昂瀵稿彲浠ラ氳繃閫夋嫨鎷ユ湁涓嶅悓瀛旂粨鏋勭殑MOFs鍘昏皟鎺с傚埗澶囩殑紕崇撼綾崇偣璐熻澆鍨婱OF钖勮啘涓嶄粎鍏鋒湁鑹ソ鐨勫艦璨屽拰鍏夊閫忔槑搴︼紝鑰屼笖琛ㄧ幇鍑烘嘗孌靛彲璋冪殑鍏夎嚧鍙戝厜鏁堝簲鍜屽厜闄愬箙鏁堝簲銆傝鐮旂┒宸ヤ綔瀹炵幇浜嗚秴灝忕⒊綰崇背鐐歸樀鍦∕OF妯℃澘涓殑鍙帶鍚堟垚錛屽茍鍙戝睍浜嗘柊鍨婥Ds@MOF澶嶅悎鍏夐檺騫呮潗鏂欙紝鍙戣〃浜庛婂痙鍥藉簲鐢ㄥ寲瀛︺?Angew. Chem. Int. Ed. 2017, DOI: 10.1002/anie.201702162)銆?/span>
銆銆鍚屾湡錛岃鐮旂┒鍥㈤槦鍒跺浜嗚兘澶熼珮鏁堥夋嫨鎬ф嫻嬫尌鍙戞ф湁鏈虹墿鐨勫崯鍟夊熀PIZA-1钖勮啘鏉愭枡(Small, 2017, 1, 1604035)錛屾帰绱簡MOF钖勮啘鐨勭敓闀垮彇鍚戙佸帤搴︺佷慨楗板熀搴曠瓑鍥犵礌瀵筂OF钖勮啘鎬ц兘鐨勫獎鍝嶏紝寮鍙戜簡涓緋誨垪鍏鋒湁鎵嬫ф媶鍒嗗姛鑳藉拰鍌寲鍔熻兘鐨勮杽鑶滄潗鏂?Chem. Commun., 2017, 53, 1470錛汚CS Appl. Mater. Interfaces, 2017, 9, 7259錛汭norg. Chem., 2017, 56, 3526錛汵anoscale 2017, DOI:10.1039/C7NR02284K)銆?/span>
銆銆璇ョ爺絀惰幏寰椾腑縐戦櫌鎴樼暐鎬у厛瀵肩鎶涓撻」(B綾?銆佸浗瀹跺熀閲戝鈥滄棤鏈?鏈夋満鏉傚寲鍔熻兘鏉愭枡鈥濆垱鏂扮兢浣撱佸浗瀹舵澃鍑洪潚騫村熀閲戙佸浗瀹惰嚜鐒剁瀛﹀熀閲戦潚騫撮」鐩佺寤虹渷鑷劧鍩洪噾闈笂欏圭洰浠ュ強緇撴瀯鍖栧鍥藉閲嶇偣瀹為獙瀹や紭縐闈掑勾璇鵑鐨勮祫鍔┿?/span>
鍏嶈矗澹版槑錛氶儴鍒嗚祫鏂欐潵婧愪簬緗戠粶錛岃漿杞界殑鐩殑鍦ㄤ簬浼犻掓洿澶氫俊鎭強鍒嗕韓錛屽茍涓嶆剰鍛崇潃璧炲悓鍏惰鐐規(guī)垨璇佸疄鍏剁湡瀹炴э紝
涔熶笉鏋勬垚鍏朵粬寤鴻銆備粎鎻愪緵浜ゆ祦騫沖彴錛屼笉涓哄叾鐗堟潈璐熻矗銆傚娑夊強渚墊潈錛岃鑱旂郴鎴戜滑鍙婃椂淇敼鎴栧垹闄ゃ?br>閭錛歩nfo@polymer.cn
錛堣矗浠葷紪杈戯細shu錛?
