 | 濉戞枡 | 姍¤兌 | 綰ょ淮 | 娑傛枡涓庢補澧?/a> | 鑳剁矘鍓?/a> | 澶嶅悎鏉愭枡 | 鐭沖寲 | 鍖栧伐 | 浠櫒浠〃 | 鏂頒駭涓?/a> | 涓撻 | 榪斿洖棣栭〉 |
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| 濉戞枡 | 姍¤兌 | 綰ょ淮 | 娑傛枡涓庢補澧?/a> | 鑳剁矘鍓?/a> | 澶嶅悎鏉愭枡 | 鐭沖寲 | 鍖栧伐 | 浠櫒浠〃 | 鏂頒駭涓?/a> | 涓撻 | 榪斿洖棣栭〉 |
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鍋舵愛鍩哄厜鐑噧鏂欙紙PTM錛夎璁や負鏄お闃寵兘鐑噧鏂欏驚鐜埄鐢ㄩ鍩熷叧閿殑鏉愭枡涔嬩竴錛屽挨鍏舵槸鍦ㄤ綆娓╃幆澧冧腑錛屽洜涓哄畠浠叿鏈夊湪浣庢俯涓嬮暱鏃墮棿鍌ㄥ瓨鐨勮兘鍔涖佸彲鎺х殑鐑噺閲婃斁錛屽寲瀛︽垚鍒嗙ǔ瀹氱瓑浼樺娍銆?/span>PTM鐨勫偍鐑兘閲忓瘑搴︽槸鍏朵綆娓╁簲鐢ㄧ殑鍩虹錛屽叾鍌ㄥ瓨娼滅儹鐨勮兘鍔涳紙鑳介噺瀵嗗害錛?/span>ED錛変富瑕佸彇鍐充簬欏哄弽寮傛瀯浣撲箣闂寸殑鑳界駭宸紙螖E錛夊拰寮傛瀯鍖栫▼搴︼紙DI錛夈傚洜姝わ紝鍦ㄥ垎瀛愬昂搴︿笂錛屼紭鍖栬兘綰у拰寮傛瀯鍖栧姩鍔涘瀵逛簬鎻愰珮PTM鐨勮兘閲忓瘑搴﹂潪甯擱噸瑕併?/span>鐩墠錛岀敱浜庤嚜韜垎瀛愮粨鏋勭殑闄愬埗錛屽鑷村伓姘熀鍏夌儹鐕冩枡鍒嗗瓙鑳介噺瀵嗗害浣庝笖鏀劇儹娓╁害楂橈紝浣垮叾鍦ㄤ綆娓╃幆澧冨簲鐢ㄩ鍩熼潰涓村法澶х殑鎸戞垬銆?/span>
閰嶄綅閿湪鐗瑰畾鏉′歡涓嬶紙濡傚厜錛屽姏絳夛級鍙互鏂紑騫跺鍘燂紝榪欑閿殑鎬ц川琚箍娉涚敤鏉ユ瀯絳戝悇縐嶅搷搴旀ф潗鏂欏拰鑷慨澶嶆潗鏂欍?/span>榪戞棩錛屽ぉ媧ュぇ瀛﹀皝浼熸暀鎺堝洟闃熸彁鍑哄埗澶囦簡涓緋誨垪閰嶄綅閿皟鎺у伓姘嫰鍖栧悎鐗?/span>-鐭沖ⅷ鐑潅鍖栨潗鏂欙紝鍙戠幇閰嶄綅閿敭鑳藉彲浠ュ拰鍏夌儹鑳藉悓鏃惰繘琛屽瓨鍌ㄥ拰閲婃斁錛屼嬌寰楁墍鍒跺鐨勫厜鐑潗鏂欑殑鑳介噺瀵嗗害澶уぇ鎻愰珮錛?/span>720 J g-1錛夈?/span>榪涗竴姝ユ瀯寤轟簡鍙湪浣庢俯涓嬭繍琛岀殑鑳介噺寰幆鍒╃敤緋葷粺銆傝欏瑰伐浣滃湪鍒嗗瓙璁捐鐨勫熀紜涓婏紝鍚堟垚浜嗗叿鏈夌：閰稿熀鍥㈢殑鍋舵愛鑻寲鍚堢墿-鐭沖ⅷ鐑潅鍖栨潗鏂欙紙G-Azo錛夛紝闅忓悗寮曞叆閰嶄綅閿皢G-Azo榪炴帴錛屽埗澶囧緱鍒頒簡鍏夊搷搴斿伓姘嫰鍖栧悎鐗?/span>-鐭沖ⅷ鐑?/span>-閲戝睘閰嶄綅鏉傚寲鏉愭枡錛?/span>G-Azo-M錛夈?/span>閰嶄綅閿殑寮曞叆鎻愰珮浜?/span>G-Azo欏哄弽寮傛瀯浣撲箣闂寸殑鑳界駭宸紝榪涜屽ぇ澶ф彁楂樹簡鍏惰兘閲忓瘑搴︼紝瀹炵幇浜嗗厜鐑兘鍜岄敭鑳藉湪浣庢俯涓嬬殑瀛樺偍鍜屽彲鎺у埄鐢ㄣ?/span>褰撶傳澶栧厜鐓у皠鏃訛紝G-Azo鍙戠敓鍙嶅紡-欏哄紡寮傛瀯鍖栵紝閰嶄綅閿柇寮錛屽偍瀛樺厜鐑兘鍜岄敭鑳斤紱褰撳彲瑙佸厜鐓у皠鏃訛紝G-Azo鍙戠敓欏哄紡-鍙嶅紡寮傛瀯鍖栵紝閰嶄綅閿啀嬈¤嚜鍙戝艦鎴愶紝鍚屾椂閲婃斁鍏夌儹鑳藉拰閿兘銆傚湪姝ゅ熀紜涓婏紝鍒╃敤鐜艦鍣ㄤ歡璁捐浜嗚兘閲忓驚鐜埄鐢ㄧ郴緇?/span>錛岄氳繃灝嗘墍鍒跺鐨?/span>G-Azo-M浣滀負鐑簮錛屼負鐩稿彉鏉愭枡渚涚儹錛屽疄鐜頒簡鑳介噺鐨勫驚鐜埄鐢ㄤ笌瀹氬悜杈撳嚭銆?/span>
鍥炬枃瀵艱
鍥?/span>1.G-Azo-M鑷粍瑁呰啘鍏夋帶閰嶄綅閿殑鏂紑鍜屽艦鎴愮粨鏋勭ず鎰忓浘銆?/span>
錛?/span>a錛夊浐鎬?/span>G-Azo-Mg鑷粍瑁呰啘鍏夋帶閰嶄綅閿殑鏂紑鍜屽艦鎴愮粨鏋勭ず鎰忓浘銆傦紙b錛?/span>G-Azo-Mg鐨勮兘綰хず鎰忓浘銆?/span>
鍥?/span>2.鍦ㄦ憾娑蹭腑閰嶄綅閿殑瑙ｇ鍜屽艦鎴?/span>銆?/span>
G-Azo-Mg緇勮浣撳湪DMF婧舵恫涓彲閫嗗艦鎴愬拰瑙ｇ紺烘剰鍥撅紙a錛夐樁孌?/span>1銆侊紙b錛夐樁孌?/span>2鍜岋紙c錛夐樁孌?/span>3銆傦紙d-f錛夌傳澶栧厜鍜屽彲瑙佸厜浜ゆ浛鐓у皠涓嬶紝G-Azo-Mg鐨?/span>DMF婧舵恫闃舵1銆?/span>2鍜?/span>3涓殢鏃墮棿鍙樺寲鐨勭傳澶?/span>-鍙鍚告敹鍏夎氨銆傦紙g-i錛夐樁孌?/span>1銆?/span>2鍜?/span>3涓紝330鍜?/span>660 nm澶勭殑鍚告敹寮哄害闅忔椂闂村彉鍖栨洸綰褲?/span>
鍥?/span>3.鍦ㄥ浐鎬佷笅G-Azo-Mg鑶滅殑鍙嗗厜寮傛瀯鍖栦笌鍏夌儹鑳藉拰閿創鐨勫瓨鍌ㄥ拰閲婃斁銆?/span>
錛?/span>a錛?/span>G-Azo-Mg鐨?/span>TEM鍥俱傦紙b錛?/span>G-Azo-Mg鐨?/span>XRD鍥捐氨銆傦紙c錛夊湪绱鍏夊厖鐑?/span>3灝忔椂鍜岃摑鍏夋斁鐑?/span>4灝忔椂涓?/span>G-Azo鍜?/span>G-Azo-Mg-x錛?/span>x=1錛?/span>2錛?/span>3錛夎杽鑶滅殑Mg 2p XPS鍏夎氨銆?/span>G-Azo鍜?/span>G-Azo-Mg-x錛?/span>x=1錛?/span>2錛?/span>3錛夎杽鑶滃湪瀹ゆ俯錛?/span>25.0 ?C錛変笅錛?/span>d錛夊厖鐑拰錛?/span>e錛夋斁鐑繃紼嬩腑鐨勫紓鏋勫寲紼嬪害銆傦紙f錛?/span>G-Azo鍜?/span>G-Azo-Mg-x錛?/span>x=1錛?/span>2錛?/span>3錛夎杽鑶滅殑涓綰у姩鍔涘甯告暟瀵規瘮銆傦紙g錛?/span>G-Azo鍜?/span>G-Azo-Mg-x錛?/span>x=1錛?/span>2錛?/span>3錛夎杽鑶?/span>DSC鏀劇儹鏇茬嚎銆傦紙h錛夎兘閲忓瘑搴︿互鍙婏紙i錛夐敭鐒撳拰鍏夌儹鑳界殑鍗犳瘮銆?/span>
鍥?/span>4.G-Azo-M鑶滃湪涓嶅悓鏉′歡涓嬬殑鍌ㄧ儹鍜屾斁鐑兘鍔涖?/span>
錛?/span>a錛?/span>G-Azo鍜?/span>G-Azo-M錛?/span>M = Mg2 銆?/span>Fe3 鍜?/span>Ni2 錛夌殑DSC鏇茬嚎銆傦紙b錛夎兘閲忓瘑搴﹀拰閲戝睘鍏冪礌鍚噺鐨勫叧緋匯傦紙c錛?/span>G-Azo-Mg鍦ㄤ笉鍚屾潯浠朵笅鏀劇儹鐨勫厜鐑兘姣斾緥鍙樺寲銆?/span>G-Azo-Mg錛?/span>d錛夊湪榛戞殫涓拰錛?/span>e錛夊湪钃濆厜涓嬫斁鐑殑DSC鏇茬嚎銆傦紙f錛?/span>Azo銆?/span>G-Azo銆?/span>G-Azo-Mg鍜?/span>G-Azo-Fe鐨勮兘閲忓瘑搴︿笌鍔熺巼瀵嗗害鐨勫叧緋匯傦紙g錛夎繎騫存潵錛屽伓姘嫰鍩哄お闃寵兘鐑噧鏂欑殑鑳介噺瀵嗗害瀵規瘮銆傦紙h錛夊姛鐜囧瘑搴﹀姣?/span>銆?/span>
鍥?/span>5.瀹ゆ俯涓?/span>G-Azo-Mg鑶滃湪钃濆厜鍒烘縺涓嬬殑鏀劇儹榪囩▼銆?/span>
錛?/span>a錛夊湪瀹ゆ俯涓嬶紝G-Azo-Mg銆?/span>G-Azo鍜?/span>rGO鑶滃湪钃濆厜鍒烘縺涓嬫斁鐑俯搴︿笌鏃墮棿鍙樺寲鏇茬嚎銆傦紙b錛?/span>G-Azo-Mg鑶滄斁鐑繃紼嬬殑綰㈠鐑儚鍥俱?/span>
鍥?/span>6.鍦ㄥ娓╁拰浣庢俯涓嬪熀浜庣幆褰㈠櫒浠惰璁＄殑鑳介噺寰幆鍒╃敤緋葷粺銆?/span>
錛?/span>a錛夊湪瀹ゆ俯涓嬶紝G-Azo-Mg鑶滃湪钃濆厜鍒烘縺涓嬫斁鐑俯搴︿笌鏃墮棿鍙樺寲鏇茬嚎銆傦紙b錛?/span>G-Azo-Mg鑶滄斁鐑繃紼嬬殑綰㈠鐑儚鍥俱傦紙c錛夊湪浣庢俯涓嬶紙2-3鈩?/span>錛夛紝G-Azo-Mg鑶滃湪钃濆厜鍒烘縺涓嬫斁鐑俯搴︿笌鏃墮棿鍙樺寲鏇茬嚎銆傦紙d錛変綆娓╀笅G-Azo-Mg鑶滄斁鐑繃紼嬬殑綰㈠鐑儚鍥俱?/span>
鐮旂┒緇撴灉琛ㄦ槑褰撳姞鍏ヤ笉鍚岄噾灞炵瀛愯繘琛岄厤浣嶆椂錛屽叾鍏夌儹鎬ц兘涓嶅悓錛屼絾閮戒紭浜庢湭閰嶄綅浣撶郴鐨勫厜鐑ц兘銆傚叾鍏夌儹鎬ц兘涓庝綋緋諱腑閰嶄綅閲戝睘鐨勫厓绱犲惈閲忔湁鍏籌紝閲戝睘鍏冪礌鍚噺瓚婇珮錛屽厜鍌ㄧ儹鑳介噺瀵嗗害瓚婂ぇ銆?/span>鍏朵腑錛岄晛閲戝睘閰嶄綅浣撶郴G-Azo-Mg鍏鋒湁杈冮珮鐨勮兘閲忓瘑搴?/span>200.0 Wh kg-1鍜屽姛鐜囧瘑搴?/span>2871.1Wh kg-1銆傞厤浣嶄綋緋葷殑瀛樺湪鏈夊埄浜庢潗鏂欒嚜涓繪垚鑶滐紝寰楀埌鏌旀у伓姘嫰-鐭沖ⅷ鐑?/span>-闀侀厤浣嶆潅鍖栨潗鏂欒啘錛屽叾鍘氬害綰︿負5寰背銆傝繘涓姝ユ祴璇曞叾鍦ㄤ綆娓╀笅錛?/span>2.0-3.0 ?C錛夌殑钃濆厜嬋鍙戠儹閲婃斁鎬ц兘錛屽叾鏀劇儹娓╁害楂樿揪40.0 鈩?/span>銆傛墍閲婃斁鐨勭儹鑳戒紶閫掔粰鐩稿彉鏉愭枡錛屼嬌鐩稿彉鏉愭枡铻嶅寲錛屽畾鍚戞祦鍔紝瀹炵幇浜嗚兘閲忕殑鍙帶杈撳嚭涓庡驚鐜埄鐢ㄣ?/span>
璇ョ爺絀舵彁鍑虹殑閰嶄綅閿皟鎺у伓姘嫰鍖栧悎鐗?/span>-鐭沖ⅷ鐑潅鍖栨潗鏂欎負瀹炵幇浣庢俯涓嬮珮鑳介噺瀵嗗害澶槼鑳界儹鐕冩枡鐨勫厜鐑瓨鍌ㄥ強杞崲鎻愪緵浜嗗彲鑳芥с傜浉鍏崇爺絀舵垚鏋滆繎鏈熶互鈥淯tilisation of photo-thermal energy and bond enthalpy based on optically triggered formation and dissociation of coordination bonds鈥?/span>涓洪鍙戣〃鍦ㄦ湡鍒?/span>Nano Energy 錛?/span>DOI: 10.1016/j.nanoen.2021.106401錛変笂錛屾枃绔犵涓浣滆呬負鍗氬＋鐢熺帇鎱э紝閫氳浣滆呬負鍐閽版暀鎺?/span>鍜?/span>灝佷紵鏁欐巿銆傝欏圭爺絀跺彈鍒板浗瀹惰嚜鐒剁瀛﹀熀閲戦噸鐐歸」鐩殑鏀寔銆?/span>
澶╂觸澶у灝佷紵鍥㈤槦闀挎湡鑷村姏浜庡厜鐑兘鏉愭枡鐨勭爺絀訛紝榪戝勾鏉ヨ鍥㈤槦鍦ㄥ浗瀹惰嚜鐒剁瀛﹀熀閲戞澃鍑洪潚騫村熀閲戦」鐩侀噸鐐歸」鐩互鍙婄鎶閮ㄩ噸鐐圭爺鍙戠瓑欏圭洰鐨勬敮鎸佷笅鍦ㄥ伓姘嫰-紕蟲ā鏉垮寲鏉愭枡錛?/span>Nanoscale, 2012, 4, 6118錛?/span>J. Mater. Chem. A, 2015, 3, 16453錛?/span>Nanoscale, 2015, 7, 16214錛?/span>Journal of Materials Chemistry A. 2015, 3, 11787錛?/span>J. Mater. Chem. A, 2016, 4, 8020-8028錛?/span>ACS Appl. Mater. Inter., 2017, 9, 4066錛?/span>Chemsuschem, 2017, 10, 1395錛?/span>Chemical Society Reviews. 2018, 47, 7339錛?/span>Energy Storage Materials, 2019. 24: 662錛?/span>J. Mater. Chem. A, 2019, 7, 97錛?/span>Energy Storage Materials, 2020, 24, 662錛夈佸伓姘嫰鏈夋満鍒嗗瓙鍜岃仛鍚堢墿錛?/span>J. Mater. Chem. A, 2020, 8, 18668錛?/span>Macromolecules, 2019, 52, 4222錛?/span>Composites Science and Technology, 2019, 169: 158錛?/span>Chinese Journal of Polymer Science. 2019 , 37(12): 1183錛?/span>銆?/span>鍋舵愛鑻?/span>-鐩稿彉鏉愭枡錛?/span>Adv. Funct. Mater., 2020, 2008496錛?/span>Composites Communications, 2020, 21, 100402錛?/span>Composites Communications, 2021, 23, 100575錛夌瓑鏉愭枡鐨勭爺絀跺拰璁捐涓婂彇寰椾簡涓緋誨垪鐨勫師鍒涙ф垚鏋溿?/span>
鐩稿叧閾炬帴
https://www.sciencedirect.com/science/article/pii/S221128552100656X