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褰撳墠浣嶇疆錛?棣栭〉 >> 璧勮 >> 綰ょ淮 >> 琛屼笟鍔ㄦ?/a> >> 姝ｆ枃

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鍥?/span> 3 錛?/span>a錛?/span> UiO-66-NH2@PAN鍦?/span>涓?/span>鍚?/span>鍙?/span>搴?/span>鏃?/span>闂?/span>鐨?/span>鍘?/span>闄?/span>鏁?/span>鐜?/span>鏇?/span>綰?/span>鍜?/span>錛?/span>b錛?/span>鍦?/span>涓?/span>鍚?/span>鐨?/span>鍚?/span>鎴?/span>鏃?/span>闂?/span>涓?/span>CEES鐨?/span>鍘?/span>闄?/span>鏁?/span>鐜?/span> 錛?/span>c錛?/span>鍦?/span>鍚?/span>鎴?/span>榪?/span>紼?/span>涓?/span>錛?/span>娣?/span>鍔?/span>鍜?/span>涓?/span>娣?/span>鍔?/span>TFA鐨?/span>UiO-66-NH2綺?/span>鏈?/span>瀵?/span>CEES鐨?/span>鍘?/span>闄?/span>鏁?/span>鐜?/span>錛?/span>錛?/span>d錛?/span>涓?/span>鍚?/span>pH涓?/span>UiO-66-NH2@PAN-2h瀵?/span>CEES鐨?/span>鍘?/span>闄?/span>鏁?/span>鐜?/span>闄?/span>瑙?/span>2h錛?/span>闄?/span>瑙?/span>鏃?/span>闂?/span>48h錛?/span>錛?/span>e錛?/span>瑙?/span>姣?/span>48灝?/span>鏃?/span>鍚?/span>瀵?/span>浜?/span>鍝?/span>榪?/span>琛?/span>鍏?/span>鎵?/span>鎻?/span>鐩?/span>嫻?/span>錛?/span>f錛?/span> UiO-66-NH2@PAN-2h鏆?/span>闇?/span>浜?/span>CEES 72灝?/span>鏃?/span> 鏍?/span>紓?/span>鍏?/span>鎸?/span>姘?/span>璋?/span>錛?/span>鍦?/span>H2SO4/DMSO涓?/span>娑?/span>鍖?/span>錛?/span>g錛?/span>鍙?/span>鑳?/span>鐨?/span>UiO-66-NH2鍜?/span>CEES鐨?/span>琛?/span>闈?/span>鍙?/span>搴?/span>銆?/span>

UiO-66-NH2涓?/span>瀵?/span>鐨?/span>瀛?/span>闅?/span>鐜?/span>鏈?/span>鍒?/span>浜?/span>鎹?/span>鑾?/span>CEES錛?/span>Zr-OH媧?/span>鎬?/span>涓?/span>蹇?/span>鍏?/span>鏈?/span>寰?/span>寮?/span>鐨?/span>鍙?/span>鎺?/span>榪?/span>鎬?/span>銆?/span>鐒?/span>鍚?/span>閫?/span>榪?/span>浜?/span>鐢?/span>鑺?/span>棣?/span>鍙?/span>浠?/span>鍙?/span>搴?/span>錛?/span>浣?/span>姘?/span>鍘?/span>瀛?/span>鍙?/span>鍒?/span>Zr-O鎴?/span>鑺?/span>鐜?/span>鐨?/span>鏀?/span>鍑?/span>錛?/span>浠?/span>鑰?/span>浣?/span>C-Cl閿?/span>鏂?/span>瑁?/span>銆?/span>涔?/span>鍚?/span>錛?/span>浣?/span>涓?/span>浜?/span>鏍?/span>璇?/span>鍓?/span>鐨?/span>紜?/span>鍘?/span>瀛?/span>浼?/span>鏀?/span>鍑?/span>浜?/span>鐢?/span>紕?/span>錛?/span>閫?/span>榪?/span>鍒?/span>瀛?/span>闂?/span>鐜?/span>鍖?/span>灝?/span>CEE杞?/span>鍖?/span>涓?/span>鐜?/span>鐘?/span>鐨?/span>紜?/span>紱?/span>瀛?/span>銆?/span>鏈鍚?/span>錛?/span>鍦?/span>MOF琛?/span>闈?/span>鍚?/span>闄?/span>瓚?/span>澶?/span>鐨?/span>姘?/span>錛?/span>100鈩?/span>涔?/span>鍓?/span>鐨?/span>TGA緇?/span>鏋?/span>琛?/span>鏄?/span>錛?/span>鏈?/span>鍒?/span>浜?/span>MOF鍌?/span>鍖?/span>鍓?/span>鍦?/span>姘?/span>-鍥?/span>鐩?/span>浜?/span>浣?/span>鐢?/span>榪?/span>紼?/span>涓?/span>姘?/span>瑙?/span>寰?/span>鍒?/span>2-緹?/span>涔?/span>鍩?/span>涔?/span>鍩?/span>紜?/span>閱?/span>銆?/span>鍥?/span>姝?/span>錛?/span>鍙?/span>鎺?/span>榪?/span>鐨?/span>瀛?/span>緇?/span>鏋?/span>銆?/span>MOF涓?/span>鏃?/span>鏈?/span>鍜?/span>鏈?/span>鏈?/span>鎴?/span>鍒?/span>鐨?/span>瀛?/span>鍦?/span>瀵?/span>浜?/span>CWAs鐨?/span>瑙?/span>姣?/span>鑷?/span>鍏?/span>閲?/span>瑕?/span>銆?/span>


鎬?/span>涔?/span>錛?/span>鎴?/span>浠?/span>宸?/span>緇?/span>鎴?/span>鍔?/span>寮鍙?/span>浜?/span>涓縐?/span>鍙?/span>鎵?/span>灞?/span>鐨?/span>鏃?/span>妯?/span>鏉?/span>鏂?/span>娉?/span>錛?/span>鍦?/span>PAN綰?/span>綾?/span>綰?/span>緇?/span>涓?/span>鐢?/span>鎴?/span>UiO-66-NH2錛?/span>鐢?/span>浜?/span>蹇?/span>閫?/span>闄?/span>瑙?/span>CWAs錛?/span>鏂?/span>娉?/span>鍒?/span>涓?/span>涓?/span>涓?/span>綆鍗?/span>姝?/span>楠?/span>錛?/span>闈?/span>鐢?/span>綰?/span>涓?/span>鍜?/span>鍘?/span>浣?/span>姘?/span>鎬?/span>鐢?/span>闀?/span>銆?/span>TFA浣?/span>涓?/span>璋?/span>鑺?/span>鍓?/span>鐨?/span>寮?/span>鍏?/span>闈?/span>甯?/span>鏈?/span>鍒?/span>浜?/span>鍦?/span>綰?/span>綾?/span>綰?/span>緇?/span>涓?/span>褰?/span>鎴?/span>鑷?/span>瀵?/span>鐨?/span>閰?/span>浣?/span>閰?/span>浣?/span>錛?/span>紜?/span>淇?/span>MOF綰?/span>綾?/span>綺?/span>瀛?/span>榪?/span>緇?/span>鍒?/span>鏁?/span>鍦?/span>鍖?/span>瑕?/span>鍦?/span>綰?/span>緇?/span>涓?/span>錛?/span>鑰?/span>涓?/span>鏄?/span>鑱?/span>闆?/span>銆?/span>姝?/span>澶?/span>錛?/span>TFA鐨?/span>浣?/span>鐢?/span>榪?/span>瀵?/span>鑷?/span>緙?/span>澶?/span>綈?/span>緙?/span>闄?/span>鐨?/span>澧?/span>鍔?/span>錛?/span>鏈?/span>鍔?/span>浜?/span>鎻?/span>楂?/span>瑙?/span>姣?/span>鑳?/span>鍔?/span>銆?/span>鐢?/span>浜?/span>UiO-66-NH2鍏?/span>鏈?/span>涓?/span>瀵?/span>鐨?/span>瀛?/span>闅?/span>鐜?/span>銆?/span>緙?/span>闄?/span>閲?/span>灞?/span>Zr媧?/span>鎬?/span>涓?/span>蹇?/span>銆?/span>鍦?/span>綰?/span>緇?/span>涓?/span>鐨?/span>楂?/span>搴?/span>鍒?/span>鏁?/span>鎬?/span>浠?/span>鍙?/span>MOF鐨?/span>楂?/span>姣?/span>琛?/span>闈?/span>縐?/span>錛?/span>鎴?/span>浠?/span>鍒?/span>澶?/span>鍜?/span>浼?/span>鍖?/span>鐨?/span>UiO-66-NH2緇?/span>鐗?/span>鍦?/span>48灝?/span>鏃?/span>鍚?/span>閫?/span>榪?/span>瀵?/span>鑺?/span>瀛?/span>綾?/span>妯?/span>鎷?/span>鐗?/span>CEES鐨?/span>鎹?/span>鑾?/span>銆?/span>鍙?/span>搴?/span>鍜?/span>姘?/span>瑙?/span>鍙?/span>浠?/span>鏈?/span>鏁?/span>鍦?/span>鍘?/span>闄?/span>楂?/span>杈?/span>97.7%鐨?/span>CEES錛?/span>72灝?/span>鏃?/span>鍒?/span>鍙?/span>杈?/span>98.94%銆?/span>鍊?/span>寰?/span>娉?/span>鎰?/span>鐨?/span>鏄?/span>錛?/span>榪?/span>浜?/span>鍚?/span>鎴?/span>鐨?/span>MOF緇?/span>鐗?/span>鍏?/span>鏈?/span>鍑?/span>鑹?/span>鐨?/span>鏌?/span>闊?/span>鎬?/span>銆?/span>楂?/span>閫?/span>姘?/span>鎬?/span>鍜?/span>鑰?/span>媧?/span>鎬?/span>錛?/span>鍙?/span>鏂?/span>渚?/span>鍦?/span>铻?/span>鍏?/span>闃?/span>鎶?/span>鏈?/span>鍜?/span>鍙?/span>緗?/span>涓?/span>錛?/span>鍙?/span>鐢?/span>浜?/span>鐨?/span>鑲?/span>鑸?/span>閫?/span>鍜?/span>鎵?/span>閲?/span>鐢?/span>浜?/span>錛?/span>榪?/span>瀵?/span>浜?/span>瀹?/span>闄?/span>搴?/span>鐢?/span>涓?/span>鐨?/span>澶?/span>鏉?/span>鏉?/span>浠?/span>鑷?/span>鍏?/span>閲?/span>瑕?/span>銆?/span>


璇?/span>璁?/span>鏂?/span>鍏?/span>鍚?/span>絎?/span>涓浣?/span>鑰?/span>涓?/span>涓騫?/span>綰?/span>鍗?/span>澹?/span>鐢?/span>瀛?/span>浜?/span>鏄?/span>鍜?/span>鍗?/span>澹?/span>鍚?/span>寮?/span>縐鐜?/span>錛?/span>涓?/span>瑕?/span>鐮?/span>絀?/span>鏂?/span>鍚?/span>涓?/span>綰?/span>綾?/span>鏉?/span>鏂?/span>鍦?/span>鑳?/span>婧?/span>涓?/span>鐜?/span>澧?/span>涓?/span>鐨?/span>搴?/span>鐢?/span>錛?/span>甯?/span>浠?/span>鏉?/span>浠?/span>涓?/span>鏁?/span>鎺?/span>銆?/span>


鐩?/strong>鍏?/strong>閾?/strong>鎺?/strong>

Xiuling Zhang鈯?/span>, Yaxin Sun鈯?/span>, Yuanfeng Liu, Zhenyu Zhai, Shiquan Guo, Lichong Peng, Yue Qin, Congju Li* UiO-66-NH2 Fabrics: Role of Trifluoroacetic Acid as Modulator on MOF Uniform Coating on Electrospun Nanofibers and Efficient Decontamination of Chemical Warfare Agent Simulants ACS AMI, https://doi.org/10.1021/acsami.1c12751

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