 | 濉戞枡 | 姍¤兌 | 綰ょ淮 | 娑傛枡涓庢補澧?/a> | 鑳剁矘鍓?/a> | 澶嶅悎鏉愭枡 | 鐭沖寲 | 鍖栧伐 | 浠櫒浠〃 | 鏂頒駭涓?/a> | 涓撻 | 榪斿洖棣栭〉 |
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| 濉戞枡 | 姍¤兌 | 綰ょ淮 | 娑傛枡涓庢補澧?/a> | 鑳剁矘鍓?/a> | 澶嶅悎鏉愭枡 | 鐭沖寲 | 鍖栧伐 | 浠櫒浠〃 | 鏂頒駭涓?/a> | 涓撻 | 榪斿洖棣栭〉 |
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鏈夋満鍦烘晥搴?/span>鏅朵綋綆?span>鏄?/span>鏈夋満浼犳劅鍣ㄣ佸瓨鍌ㄥ櫒浠跺拰鏌旀х數璺?span>絳夋湁鏈虹數瀛愬櫒浠剁殑閲嶈緇勬垚閮ㄥ垎銆?span>鍦?/span>鏈夋満鍦烘晥搴?/span>鏅朵綋綆?span>涓紝杞芥祦瀛愪互騫寵浜庡熀搴曠殑鏂瑰悜浼犺緭浠ヨ幏寰楅珮榪佺Щ鐜囥傛湁鏈哄崐瀵間綋灞備腑楂樺害鏈夊簭鐨勫垎瀛愮粨鏋勬槸杞芥祦瀛愰珮鏁堜紶杈撶殑鍏抽敭錛屽洜姝よ皟鎺ф湁鏈哄崐瀵間綋鏈夊簭鐢熼暱瀵瑰埗澶囬珮璐ㄩ噺鏈夋満鐢靛瓙鍣ㄤ歡鑷沖叧閲嶈銆?/span>
榪戞棩錛屽北涓滃ぇ瀛︾儹縐戝涓庡伐紼嬬爺絀朵腑蹇冪帇閼厹璇鵑緇勫湪銆?/span>Applied Surface Science銆嬩笂鍙戣〃浜嗛涓?/span>鈥?/span>Atomistic insights into dynamic growth of pentacene thin films on metal surfaces functionalized with self-assembled monolayers鈥濈殑璁烘枃銆傝璁烘枃鐮旂┒浜嗘湁鏈哄皬鍒嗗瓙鍗婂浣撳茍浜旇嫰錛?/span>pentacene錛夊湪涓嶅悓鑷粍瑁呭崟鍒嗗瓙灞傦紙SAM錛変慨楗扮殑閲戯紙Au錛夎〃闈笂鐨勫姩鍔涘鐢熼暱琛屼負錛屼負鏈夋満鐢靛瓙鍣ㄤ歡鐨勫埗澶囨彁渚涗簡閲嶈鐨勭悊璁烘寚瀵箋傚北涓滃ぇ瀛︾儹縐戝涓庡伐紼嬬爺絀朵腑蹇冪澹爺絀剁敓鐜嬬淮闊負璁烘枃絎竴浣滆呫?/span>姝ょ爺絀跺緱鍒板浗瀹惰嚜鐒剁瀛﹀熀閲戠瓑璧勫姪鏀寔銆?/span>
I SAM鍜岀矖緋欏害瀵圭敓闀跨殑褰卞搷
鍥?/span>1 騫朵簲鑻湪涓嶅悓鍩哄簳涓?/span>鍔ㄥ姏瀛?/span>鐢熼暱榪囩▼銆?/span>
鍥?/span>2 錛?/span>a錛夌矖緋?/span>SAM(-CH3)鍜?/span>綺楃硻SAM(-COOH)琛ㄩ潰涓婁笉鍚屽垎瀛愬眰鐨勫鉤鍧囧炬枩瑙掗殢娌夌Н鍒嗗瓙鏁扮殑鍙樺寲銆傦紙b錛夌矖緋?/span>SAM(-CH3)鍜?/span>綺楃硻SAM(-COOH)琛ㄩ潰涓婁笉鍚屽垎瀛愬眰鐨勮川蹇冮珮搴﹂殢娌夌Н鍒嗗瓙鏁扮殑鍙樺寲銆?/span>
II 娓╁害瀵圭敓闀跨殑褰卞搷
鍥?/span>3 鍦?/span>350鍒?/span>500 K鐨勫熀搴曟俯搴︿笅錛岋紙a-d錛夌矖緋?/span>SAM(-CH3)琛ㄩ潰鍜岋紙e-h錛夌矖緋?/span>SAM(-COOH)琛ㄩ潰涓婏紝騫朵簲鑻垎瀛愰棿鐩鎬簰浣滅敤鑳斤紙EPen-Pen錛夈?/span>騫朵簲鑻?/span>鍜?/span>SAM鍒嗗瓙闂寸浉浜掍綔鐢ㄨ兘錛?/span>EPen-SAM錛変互鍙婂茍浜旇嫰鏅舵牳騫沖潎鍊炬枩瑙掗殢娌夌Н鍒嗗瓙鏁扮殑鍙樺寲銆?/span>
III 鑷敱鑳藉鐢熼暱鐨勫獎鍝?/span>
鍥?/span>4 綺楃硻SAM(-COOH)鍩?/span>搴?/span>銆?/span>ML1鍜?/span>ML2鐨勮〃闈㈣嚜鐢辮兘鍒嗗竷銆?/span>
浣滆呯畝浠?/strong>
鐜嬮懌鐓?/span>錛屽北涓滃ぇ瀛︾儹縐戝涓庡伐紼嬬爺絀朵腑蹇冨壇鏁欐巿錛屽崥澹敓瀵煎笀錛屼腑鍥藉伐紼嬬儹鐗╃悊瀛︿細浼犵儹浼犺川鍒嗕細闈掑勾濮斿憳浼氬鍛橈紝涓浗澶嶅悎鏉愭枡瀛︿細瀵肩儹澶嶅悎鏉愭枡涓撲笟濮斿憳浼氬鍛橈紝鍏ラ夆滃北涓滃ぇ瀛﹂潚騫村鑰呮湭鏉ヨ鍒掆濄備富瑕佷粠浜嬪井綰沖昂搴︿紶鐑強鑳介噺杞崲銆佺數瀛愬櫒浠剁儹綆＄悊銆佸己鍖栦紶鐑笌鑺傝兘鎶鏈佹柊鑳芥簮寮鍙戜笌鍒╃敤絳夐鍩熺殑鐮旂┒銆傚厛鍚庝富鎸佸浗瀹惰嚜鐒剁瀛﹀熀閲戙佸北涓滅渷閲嶇偣鐮斿彂璁″垝銆佸北涓滅渷鑷劧縐戝鍩洪噾絳夊欏瑰浗瀹剁駭銆佺渷閮ㄧ駭欏圭洰錛涘湪鍥藉唴澶栭噸瑕佸鏈湡鍒婂彂琛?/span>SCI璁烘枃50浣欑瘒錛屽叾涓?/span>6綃囪鏂囧叆閫夆滃皝闈㈣鏂団濄?/span>
鍘熸枃閾炬帴
https://doi.org/10.1016/j.apsusc.2021.152203