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�D1 Schematic illustration of photo-thermal dual-curing and crosslinked networks of silicone elastomers.
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�D2 (a) G'' and G'''' during in situ rheological test; (b) real-time infrared spectra (FTIR) of TE�CIN samples
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�D3 VT-IR spectra of TE�CIN10, (a) peak shift as heated from 40 to 120 ��C by 10 ��C/min, (b) peak shift during cooled from 120 to 40 ��C by 10 ��C/min. Variation of storage modulus E�� under various temperatures as a function of time, (c) IN samples, (d) TE�CIN10 samples. Normalized stress-relaxation curves, (g) TE�CIN10 samples under different temperatures and (h) elastomers containing various ionic bonds at 60 ��C, (c) Linear fitting of relaxation time (��) versus temperature according to the Arrhenius'' equation, (d) Stress relaxation activation energy (Ea) of samples with various ionic bonds.
�D4 Illustration of self-healing mechanism.
�D5 (a) Repeated macro-repairing of damaged TE�CIN10 samples. Stress-strain curves of virgin and self-healed silicone elastomers, (b) epeatedly healed TE�CIN10 samples, (c) TE�CIN10, TE�CIN20 and TE�CIN30 samples healed at 100 ��C for 12 h.
�D6 Photographs for the reprocessing of TE�CIN10 samples. (b-c) Stress-strain curves of virgin and reprocessed silicone elastomers, (b) repeatedly reprocessed TE�CIN10 samples from 80 meshes, (c) self-healing properties of repeated reprocessed TE�CIN10 samples.
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�D7 Transmittance of (a) silicone elastomers containing various ionic bonds, (b) TE�CIN10 samples with different healing times, (c) stress-strain curves and (d) storage modulus E'' and tan �� of TE�CIN10 samples after hydro-thermally treated.
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�D8 (a) Schematic of SLA-based 3D printing. (b) 3D printed various geometries from TE�CIN10 formula with different pigments, ��GDUT�� with 1.0 wt% RP�C355, ��Toothed Gears�� in turn with 0.05 wt% BP�C825, 0.05 wt% RP�C355, and 1.0 wt.% BP�C825, ��Ascendant�� with 0.05 wt% RP�C355. (c) Photographs of self-healing 3D printed ��Ascendant��. (d) Stress-strain curves of repeatedly self-healed 3D printed samples after 100 ��C for 12 h.
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Փ��朽ӣ�https://doi.org/10.1016/j.cej.2020.124142
���������n�}�M�����з����߷��ӹ⻯�W����������-ϩ���c�����W��3D��ӡ�����w��3D��ӡ���ޏͲ��ϺͶ�ܹ����l�������P�ɹ��l���ڡ�Progress in Polymer Science������Journal of Materials Chemistry C����Polymer Chemistry����Langmuir������Journal of Photochemistry & Photobiology A: Chemistry������ChemPhotoChem����Angewandte Chemie International Edition, Chemistry - ChemPhotoChem���͡�Progress in Organic Coatings����ԓ�I��TOP���H�����ڿ��ϡ�
Yan Yang, Zushan Ye, Xiaoxuan Liu*, Jiahui Su*. A Healable Waterborne Polyurethane Synergistically Cross-Linked by Hydrogen Bonds and Covalent Bonds for Composite Conductor. Journal of Materials Chemistry C, 2020, DOI: 10.1039/D0TC00551G
J. Zhou, X. Allonas, X. Liu*. Zirconium Propoxide: A Coupling Agent for the Synthesis of Multifunctional Photoinitiators. ChemPhotoChem, 2018, 2(1): 18-21.
J. Zhou, X. Allonas, X. Liu*. Synthesis and Characterization of Organozirconiums with Type-II Photoinitiator Ligands as Multifunctional Photoinitiators for Free Radical Photopolymerization. Journal of Photochemistry and Photobiology Part A: Chemistry, 2018, 356: 580-586.
J. Zhou, X. Allonas, X. Liu.* Fluorinated Organozirconiums: Enhancement of Overcoming Oxygen Inhibition in the UV-curing Film. Progress in Organic Coatings, 2018, 120: 228-233.
Yang Y, Zhang T, Liu X*. et al. Preparation and photochromic behavior of spiropyran-containing fluorinated polyacrylate hydrophobic coatings. Langmuir, 2018, 4 (51): 15812-15819
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Xiang, H.; Yin, J.; Lin, G.; Liu, X*. et al., Photo-crosslinkable, self-healable and reprocessable rubbers. Chemical. Engineering Journal. 2019, 358, 878-890.
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