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One-Pot Synthesis and Postpolymerization Functionalization of Cyclic Carbonate/Epoxide-Difunctional Polycarbonates Prepared by Regioselective Diepoxide/CO2 Copolymerization,Polym. Chem., 2016, 2016,7, 4453-4457
writer：Bing Han, Li Zhang, Hongye Zhang, Huining Ding, Binyuan Liu and Xianhong Wang
keywords：Functional Polycarbonate, Carbon Dioxide,Copolymerization
source：期刊
specific source：Polym. Chem., 2016, 2016,7, 4453-4457
Issue time：2016年

Novel aliphatic polycarbonates with tunable number of cyclic carbonate and epoxide dual functional groups have been synthesized via a (ONSO)CrCl-mediated copolymerization of 4-vinyl-1-cyclohexene diepoxide with carbon dioxide in one pot. The resulting difunctional polycarbonates with high Tg afford a versatile platform for the postpolymerization functionalization.