A trinuclear Pd-diimine catalyst for ‘core-first’ synthesis of three-arm star polyethylenes via ethylene ‘living’ polymerization
writer：K. Zhang, Z. Ye*, R. Subramanian
keywords：無
source：期刊
specific source：Macromolecules
Issue time：2009年
we have demonstrated the synthesis of a novel trinuclear Pd-diimine complex (2) and its enabled ethylene trifunctional “living” polymerization for “core-first” synthesis of star polyethylenes. Well-defined narrow-distributed threearm star polyethylenes of controllable arm lengths have been obtained by purifying the as-produced polymers. The arms of these star polymers contain a backbone of linear topology with short branching structures.