【ACS Sustainable Chemistry & Engineering】Multifunctional Ce/ZrSi Catalyst Synergistically Converting 1,4-Pentanediol Derived from Levulinic Acids to Renewable Pentadiene
作者：Shijun Liu, Yanlong Qi*, Ruilin Feng, Long Cui, Quanquan Dai, and Chenxi Bai*
關鍵字：1
論文來源：期刊
發(fā)表時間：2021年
Here, an innovative approach to produce renewable pentadiene is described: converting levulinic acids to 1,4-pentanediol, followed by dehydration to pentadiene affording 77.5% yield over a multifunctional Ce/ZrSi catalyst. Impressively, a synergistic effect between Ce and ZrSi was disclosed for the direct dehydration, and further transformation was relatively stimulated from the undesirable product 2-methyltetrahydrofuran toward pentadiene. Moreover, the direct dehydration took priority over the pentadiene synthesis among the two reaction pathways.