[Langmuir] Light-triggered Reversible Self-assembly of Gold Nanoparticle Oligomers for Tuneable SERS
writer：Lei Zhang, Liwei Dai, Yun Rong, Zhenzhong Liu, Dingyi Tong, Youju Huang and Tao Chen*
keywords：Gold nanoparticle; Self-assembly; Photoresponsive; Surface-enhance Raman spectroscopy
source：期刊
specific source：Langmuir, 2015, 31 (3), 1164–1171
Issue time：2015年
A photoresponsive amphiphilic gold nanoparticle (AuNP) is achieved through the decoration on AuNP with hydrophilic poly (ethylene glycol) (PEG) and hydrophobic photoresponsive polymethacrylate containing spiropyran units (PSPMA). Owing to photoresponsive property of spiropyran units, the amphiphilic AuNPs can easily achieve the controllable assembly/disassembly behaviours under the trigger by light. Under visible light, spiropyran units provide weak inter-molecular interactions between neighbored AuNPs, leading to isolated AuNPs in the solution. While under UV light irradiation, spiropyran units in the polymer brushes transform into merocyanine isomer with conjugated structure and zwitter-ionic state, promoting the integration of adjacent AuNPs through π-π stacking and electrostatic attractions, further leading to the formation of Au oligomers. The smart reversible AuNP oligomers exhibited switchable plasmonic coupling for tuning surface-enhanced Raman scattering (SERS) activity, which is promising for the application of SERS based sensors and optical imaging.