Yixin Han, Kunpeng Ruan and Junwei Gu*. Janus
(BNNS/ANF)-(AgNWs/ANF) thermal conductivity composite films with superior
electromagnetic interference shielding and Joule heat performances. Nano
Research, 2022, 15: 4747–4755. 2020IF=8.897.（1區(qū)材料科學(xué)Top期刊，中國(guó)科技期刊卓越行動(dòng)計(jì)劃-領(lǐng)軍類期刊項(xiàng)目，2021中國(guó)最具國(guó)際影響力學(xué)術(shù)期刊）
https://link.springer.com/article/10.1007/s12274-022-4159-z
Abstract
Highly thermal conductivity materials with excellent electromagnetic interference shielding and Joule heating
performances are ideal for thermal management in the next generation of
communication industry, artificial intelligence and wearable electronics. In this work, thermal conductivity silver nanowires (AgNWs) are prepared by polyol
thermal method using silver nitrate as the silver source and ethylene glycol as
the solvent and reducing agent, and boron
nitride (BN) is taken as raw material to prepare thermal conductivity and
insulating boron nitride nanosheets (BNNS) with the help of isopropyl
alcohol (IPA) and ultrasonication-assisted peeling method, which are compounded
with aramid nanofibers (ANF) prepared by chemical dissociation, respectively, and the
(BNNS/ANF)-(AgNWs/ANF) thermal conductivity and electromagnetic interference
shielding composite films with Janus structure are prepared by the
“vacuum-assisted filtration and hot pressing” method. The results show that Janus (BNNS/ANF)-(AgNWs/ANF) thermal
conductivity and electromagnetic interference shielding composite films exhibit “one side insulating, one side conducting” properties, the surface resistivity of
the BNNS/ANF surface is 4.7×1013 Ω, while the conductivity of the
AgNWs/ANF surface is 5275 S/cm. The (BNNS/ANF)-(AgNWs/ANF) thermal conductivity and
electromagnetic interference shielding composite film with thickness of 95 μm
has a high in-plane thermal conductivity coefficient of 8.12 W/(m·K) and excellent electromagnetic
interference shielding performance of 70 dB. The composite film also has excellent mechanical
properties (tensile strength and tensile modulus of 122.9 MPa and 2.7 GPa,
respectively). It also has good temperature-voltage response
characteristics (high Joule heating temperature at low supply voltage (5 V,
215.0oC),
fast response time (10 s)), excellent electrical stability and reliability (stable
and constant real-time relative resistance under up to 300 cycles and 1500 s of
tensile-bending fatigue work tests).
兼具優(yōu)異電磁屏蔽性能和焦耳熱性能的高導(dǎo)熱材料是下一代通訊工業(yè)、人工智能和可穿戴電子產(chǎn)品領(lǐng)域中理想的熱管理材料。本文以硝酸銀為銀源、乙二醇為溶劑和還原劑，采用多元醇熱法制備導(dǎo)熱導(dǎo)電銀納米線（AgNWs），并以氮化硼（BN）為原料，借助異丙醇（IPA）及超聲輔助剝離法制備導(dǎo)熱絕緣氮化硼納米片（BNNS），分別與化學(xué)解離制備的芳綸納米纖維（ANF）復(fù)合，經(jīng)“真空輔助抽濾-熱壓”法制備具有Janus結(jié)構(gòu)的(BNNS/ANF)-(AgNWs/ANF)導(dǎo)熱屏蔽復(fù)合膜。結(jié)果表明，Janus (BNNS/ANF)-(AgNWs/ANF)導(dǎo)熱屏蔽復(fù)合膜展現(xiàn)出“一面絕緣、一面導(dǎo)電”特性，BNNS/ANF面表面電阻率為4.7×1013 Ω，而AgNWs/ANF面電導(dǎo)率為5275 S/cm。95 μm厚的(BNNS/ANF)-(AgNWs/ANF)導(dǎo)熱屏蔽復(fù)合膜具有8.12 W/(m·K)的高面內(nèi)熱導(dǎo)率和70 dB的卓越電磁屏蔽效能。該復(fù)合膜還具有優(yōu)異的力學(xué)性能（拉伸強(qiáng)度和拉伸模量分別為122.9 MPa和2.7 GPa），良好的溫度-電壓響應(yīng)特性（如低供電電壓下的高焦耳加熱溫度（5 V、215.0oC）、快速響應(yīng)時(shí)間（10 s）），優(yōu)異的電穩(wěn)定性和可靠性（長(zhǎng)達(dá)300次、1500 s的拉伸-彎曲疲勞工作試驗(yàn)下表現(xiàn)出穩(wěn)定和恒定的實(shí)時(shí)相對(duì)電阻）。
本文亮點(diǎn)
1. 采用“真空輔助抽濾-熱壓”法制備的(BNNS/ANF)-(AgNWs/ANF)導(dǎo)熱屏蔽復(fù)合膜展現(xiàn)出“一面絕緣、一面導(dǎo)電”特性。BNNS/ANF面表面電阻率為4.7×1013 Ω，而AgNWs/ANF面電導(dǎo)率為5275 S/cm。
2. (BNNS/ANF)-(AgNWs/ANF)導(dǎo)熱屏蔽復(fù)合膜具有高達(dá)8.12 W/(m·K)的高面內(nèi)熱導(dǎo)率、70 dB的卓越電磁屏蔽效能，以及優(yōu)異的力學(xué)性能（拉伸強(qiáng)度和拉伸模量分別為122.9 MPa和2.7 GPa）。
3.
(BNNS/ANF)-(AgNWs/ANF)導(dǎo)熱屏蔽復(fù)合膜良好的溫度-電壓響應(yīng)特性（如低供電電壓下的高焦耳加熱溫度（5 V、215.0oC）、快速響應(yīng)時(shí)間（10 s））。
4.
(BNNS/ANF)-(AgNWs/ANF)導(dǎo)熱屏蔽復(fù)合膜具有優(yōu)異的電穩(wěn)定性和可靠性（長(zhǎng)達(dá)300次、1500 s的拉伸-彎曲疲勞工作試驗(yàn)下表現(xiàn)出穩(wěn)定和恒定的實(shí)時(shí)相對(duì)電阻）。