[Composites Part A]Synergistic improvement of thermal conductivities of polyphenylene sulfide composites filled with boron nitride hybrid fillers
作者：Junwei Gu*, Yongqiang Guo#, Xutong Yang#, Chaobo Liang, Wangchang Geng, Lin Tang, Nan Li, Qiuyu
關鍵字：A. Polymer-matrix composites (PMCs); B. Thermal properties; D. Compression moulding
論文來源：期刊
具體來源：Composites Part A: Applied Science and Manufacturing
發表時間：2017年
Hybrid fillers of micrometer boron nitride/nanometer boron nitride (mBN/nBN) were employed to fabricate the highly thermally conductive insulating mBN/nBN/polyphenylene sulfide ((mBN/nBN)/PPS) composites via mechanical ball-milling followed by hot-compression method. The thermally conductive coefficient (λ), dielectric constant (ε) & dielectric loss tangent (tanδ) values and thermal stabilities were all enhanced with the increasing addition of mBN/nBN hybrid fillers. The λ value was improved from 0.286 W/mK for pristine PPS matrix to 2.638 W/mK for the (mBN/nBN)/PPS composite with 60 wt% mBN/nBN (mass fraction, 2:1) hybrid fillers. Appropriate addition of the mBN/nBN hybrid fillers played a role of heterogeneous nucleation for PPS matrix. Agari model fitting revealed that the mBN/nBN hybrid fillers could be much easier to form the continuous thermally conductive channels & networks. The corresponding ε and tanδ values still maintained relatively lower level of 3.96 and 0.022, respectively. And the corresponding THeat-resistance index (THRI) value was beyond 277.8oC.
http://dx.doi.org/10.1016/j.compositesa.2017.01.019