43. Template-free Preparation of Volvox-like CdxZn1-xS Nanospheres with Cubic Phase for Efficient Photocatalytic Hydrogen Production
作者：H. Zhou, Q. Liu, W. Liu, J. Ge,* M. Lan, X. Wang, C. Wang, J. Geng, P. Wang
關鍵字：Hydrogen, Heterogeneous catalysis, Photochemistry, Nanostructures, Structure-activity Relationships
論文來源：期刊
具體來源：Chem-Asian J. 2014, 9, 811-818
發(fā)表時間：2014年
Volvox-like CdxZn1-xS solid solutions with a cubic zinc blend structure were synthesized through a template-free ethylene glycol process. Cd(Ac)(2)2H(2)O, Zn(Ac)(2)2H(2)O, and thiourea are used as the starting materials and dissolved in ethylene glycol. These reaction precursors and solvent not only contributed to control over the formation of the volvox-like spherical geometry, but also exerted vigorous domination for existence of cubic-phaseCdxZn1-xS nanostructures. As-prepared volvox-like CdxZn1-xS nanospheres have a diameter of around 100nm with extensional shells. These samples show excellent photocatalytic H-2 evolution activity from water splitting under visible-light irradiation without any cocatalyst or scaffolding, owing to their tunable band gap, cubic zinc blend structure, and unique hierarchical porous structure with a high surface area (as high as 95.2m(2)g(-1)).