Tunable bulk material with robust and renewable superhydrophobicity designed via in-situ loading of surface-wrinkled microparticles.
作者：Shanqiu Liu, Xiaotian Zhang, Stefan Seeger.
關鍵字：Renewable and robust superhydrophobicity， Mechanical robustness， Surface-wrinkled microparticles ，Tunable bulk material， Selective absorption
論文來源：期刊
發表時間：2020年
Superhydrophobic surfaces possess susceptibility towards mechanical and chemical damages as well as oil
fouling, which limits their widespread use in practical applications. Here, we demonstrate a straightforward
approach to fabricate tunable bulk material with robust and renewable superhydrophobicity by in-situ loading of
interconnected surface-wrinkled microparticles. The bulk material shows mechanochemically robust superhydrophobicity across its whole 3D volume, features renewable superhydrophobicity after extremely chemical
corrosion, and could regenerate its water repellency after oil contamination. The bulk material also features
ultrahigh efficiency (~98%) in oil-water mixtures separation, due to its selective oil absorption capability from
water. Notably, the mechanical performances, microstructures and density of the bulk material can be adjusted
on demand by simply changing the amount of loaded microparticles. Compared to the pristine commercial
melamine-formaldehyde based porous substrate (MFPS), the achieved bulk material shows up to ~230 folds
increase in Young’s modulus, ~145 folds increase in flexure stress and ~25 folds increase in tensile stress. This
strategy features great potential for designing lightweight structural materials with robust waterproof functionality as well as materials with efficient oil recovery capability from wastewater.