96.(Macro. Rapid. Commun.)Crystallizable Aliphatic Chains Enhanced Covalent Adaptable Networks: Fast Reprocessing and Improved Performance
作者：Yanlin Liu, Zhen Yu, Xiwei Xu, Binbo Wang, Hongzhi Feng, Pengyun Li, Jin Zhu, Songqi Ma*
關鍵字：熱固性樹脂，動態共價交聯高分子，結晶，回收，快速重塑
論文來源：期刊
具體來源：Macromolecular Rapid Communications
發表時間：2022年
Covalent adaptable networks (CANs) exhibit recyclability such as reprocessing, but it’s a challenge to address the contradiction between reprocessing rate and performance. Here, pendent aliphatic chain anhydride monoesters are innovatively introduced into epoxy CANs based on transesterification, which efficiently accelerates the reprocessing without sacrificing thermal and mechanical properties. The transesterification rate is raised on account of the flexible aliphatic chain-promoted segment movement and dynamic transfer auto-catalysis. When the carbon number reflecting the length of the pendent chain is 12, the epoxy CAN exhibits the fastest stress relaxation or reprocessing. Computation via molecular dynamics simulation demonstrates that the increased segmental mobility from the pendent aliphatic chains contributes to enhanced reprocessability. Interestingly, the crystallization of the pendent aliphatic chains maintains or even improves the thermal and mechanical properties. Thus, introducing a flexible and crystallizable aliphatic side chain is an innovative and efficient approach to accelerate dynamic reactions and network arrangement while improving performance.
論文鏈接： https://doi.org/10.1002/marc.202200379