Surface Acetylation of Cellulose Nanocrystal and Its Reinforcing Function for Poly(lactic acid)
writer：Ning Lin, Jin Huang, Peter R. Chang, Jiwen Feng, Jiahui Yu
keywords：Acetylation，Cellulose Nanocrystal
source：期刊
specific source：Carbohydrate Polymers, 2011, 83(4), 1834–1842.
Issue time：2011年
A novel and facile method for surface acetylation of cellulose nanocrystals (CN) was developed by reaction with acetic anhydride and hydroxyl groups on the surface of CN. The resultant acetylated cellulose nanocrystals (ACN) exhibited improved dispersion in various organic solvents and reduced polarity as compared with unmodified CN. These ACN were subsequently introduced into a poly(lactic acid) (PLA) polymeric matrix to produce fully biodegradable nanocomposites, which showed superior mechanical performance and thermal stability. This improvement was primarily attributed to uniform dispersion of the ACN and to strong interfacial adhesion between filler and matrix. This high performance and ecofriendly nanocomposite will expand the utilization of cellulose nanocrystals from renewable bioresources and the practical application of PLA-based plastic.