Preparation and properties of isotactic polypropylene obtained from MgCl2-supported TiCl4 catalyst bearing bifunctional internal donor
writer：Bin Chen ? Qiao-feng Zhang ? Li-Ping Zhao ? Xue-quan Zhang ? He-xin Zhang
keywords：Ziegler–Natta catalyst Polypropylene Molecular weight distribution Bifunctional internal donor
source：期刊
specific source：Polym. Bull. (2013) 70:2793–2800
Issue time：2013年
In this research, a novel MgCl2-supported TiCl4 catalyst in conjunction with bifunctional internal donor was synthesized. The effects of internal donor on propylene polymerization behaviors and polymer properties (morphology, Mw and MWD) were investigated. It was found that the activity of novel catalyst was higher than that of the traditional DIBP-based Ziegler–Natta catalyst, while the catalyst activity was less influenced by the ether group length of the bifunctional internal donor. It was also observed that the MWD of PP obtained by bifunctional internal donor-based catalyst was broader than that of PP made by DIBP-based Ziegler–Natta catalyst.