In-situ synthesis of hybrid nickel cobalt sulfidecarbon nitrogen nanosheet composites as highly efficient bifunctional oxygen electrocatalyst for rechargeable Zn-air batteries
作者：Jin-Zhong He, Wen-Jun Niu?, Ya-Ping Wang, Qiao-Qiao Sun, Ming-Jin Liu, Kuangye Wang, Wen-Wu Liu, Mao
關鍵字：NiCo 2 S 4 /CNNs composites Electrocatalyst Oxygen reduction reaction Oxygen evolution reaction Zn-air batteries
論文來源：期刊
具體來源：Electrochimica Acta
發表時間：2020年
In this work, an in-situ synthetic, pyrolytic and carbonized method is elaborately demonstrated to prepare the nickel cobalt sulphide (NiCo2S4) nanoparticles (NPs)/carbon nitrogen nanosheets (CNNs) com- posites as a highly efficient bifunctional oxygen electrocatalyst for rechargeable Zn-air batteries (ZABs). Specifically, the in-situ synthesized NiCo2S4 NPs confined in cages of CNNs create a well-defined elec- tron transfer hetero-interface with more exposed active sites. The combined NiCo2S4 NPs with the CNNs generate a synergistic effect, which provides effective electron transfer pathways to enhance the elec- trocatalytic behaviors, yielding a more positive half-wave potential (0.83 V) for oxygen reduction reaction (ORR) and a lower overpotential (360 mV at 10 mA cm-2 ) for oxygen evolution reaction (OER). As a proof of concept, the equipped ZABs exhibit a high peak power density of 92 mW cm-2 and a superior energy density of 1025 Wh kg-1 with robust cycling stability over 10 0 0 cycles for 180 h, which are better than that of a commercially available Pt/C-RuO2 catalyst. The findings highlight the practical viability of the NiCo2S4/CNNs composites in rechargeable ZABs and provide a new approach for the efficient synthesis of bifunctional oxygen electrocatalyst in the future.