Influence of Ammonium polyphosphate on the flame retardancy of ramie fiber reinforced poly(lactic acid) biocomposites
作者：Shumao Li, Jie Ren, Hua Yuan, Tao Yu, Weizhong Yuan.
關鍵字：poly(lactic acid), PLA, ramie, ammonium polyphosphate, composite
論文來源：期刊
具體來源：Polymer International
發表時間：2010年
Fully degradable natural fiber/degradable polymer composites have received much research attention and have various applications such as in automotive components. But flammability limits their application; it is important to improve the flame retardancy of fully degradable composites with environmentally friendly flame retardants. Flame-retarded ramie fiberreinforced poly(lactic acid) (PLA) composites were prepared using three processes: (1) PLA was blended with ammonium polyphosphate (APP), and then the resulting flame-retarded PLA was combined with ramie fibers; (2) ramie fibers underwent flame-retardant treatment with APP, which were then compounded with PLA; and (3) PLA and ramie, both of which had been flame-retarded using APP, were blended together. The APP in the composites is shown to be very effective in improving flame retardancy according UL94 test and limiting oxygen iindex measurements. Thermogravimetric analysis shows that the improved flame retardancy is due to increased char residue at high temperature. The loading of APP disturbs the compatibility between PLA and fibers, which can be directly observed using scanning electron microscopy. Furthermore it has an influence on the dynamic mechanical properties and mechanical properties according dynamic mechanical analysis and mechanical measurements. The results show that composites produced using the third process not only have the best flame retardancy but also comparatively better mechanical properties