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A novel Cu-II-azido-pyrazine framework with 3D-4(2).6(3).8-topology: Crystal structure and magnetic property
writer：Yang-Hui Luo, Yong-Hong Lu, Bai-Wang Sun*
keywords：CuII–azido-pyrazine, Methyl groups control, Magnetic property
source：期刊
Issue time：2013年
The methyl groups of 2,3-dimethylpyrazine (2,3-DMP) in [Cu2(N3)4(2,3-DMP)]n (1) lead to the formation of a novel 3D-42.63.8-topology, which exhibits 2D honeycomb layer completed by CuIIions, di-EO and di-EE azido, and featuring strong antiferromagnetic coupling.