Accessing Structure and Dynamics of Mobile Phase in Organic Solids by Real-Time T1C Filter PISEMA NMR Spectroscopy
作者：Zhang RC, Chen YZ, Chen TH, Sun PC, Li BH, Ding DT
關(guān)鍵字：Mobile Component, Organic Solids, NMR, PISEMA, Dipolar Coupling
論文來源：期刊
具體來源：Journal of Physical Chemistry A 2012, 116, 979–984
發(fā)表時(shí)間：2012年
The structure and dynamic behavior of mobile components play a significant role in determining properties of solid materials. Herein, we propose a novel real-time spectrumediting method to extract signals of mobile components in organic solids on the basis of the polarization inversion spin exchange at magic angle (PISEMA) pulse sequence and the difference in 13C T1 values of rigid and mobile components. From
the dipolar splitting spectrum sliced along the heteronuclear dipolar coupling dimension of the 2Dspectrum, the structural and dynamic information can be obtained, such as the distances between atoms, the dipolar coupling strength, the order parameter of the polymer backbone chain, and so on. Furthermore, our proposed method can be used to achieve the separation of overlapped NMR signals of mobile and rigid phases in the PISEMA experiment. The high efficacy of this 2D NMR method is demonstrated on organic solids, including crystalline L-alanine, semicrystalline polyamide-6, and the natural abundant silk fibroin.