Ionic Hydrocarbon Surfactants for Emulsification and Dispersion Polymerization in Supercritical CO2.
writer：Tan, Bien; Lee, Jun-Young; Cooper, Andrew I.
keywords：ScCO2
source：期刊
specific source：Macromolecules (2006), 39(22), 7471-7473.
Issue time：2006年
A novel twin-tail quaternary ammonium hydrocarbon surfactant was synthesized using oligovinyl acetate (OVAc) as the CO2-philic unit. It was then shown that this stabilizer is an emulsifier for water and an efficient stabilizer for the dispersion polymn. of pyrrole in supercrit. carbon dioxide (scCO2).