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Functional Oligo(vinyl acetate) CO2-philes for Solubilization and Emulsification
writer:an, Bien; Cooper, Andrew I.
keywords:ScCO2
source:期刊
specific source:Journal of the American Chemical Society (2005), 127(25), 8938-8939
Issue time:2005年

The development of inexpensive and biodegradable CO2-sol. ligands, surfactants, and phase transfer agents is an important goal in the implementation of supercrit. fluid technol.  We report here a potentially generic synthetic route to inexpensive oligo(vinyl acetate) CO2-philes for applications such as solubilization and emulsification.  These materials are shown to outperform more expensive fluorinated surfactants in particular applications.