3D Ti3C2Tx MXene/C hybrid foam/epoxy nanocomposites with superior electromagnetic interference shielding performances and robust mechanical properties
writer：[8] Lei Wang, Hua Qiu, Ping Song, Yali Zhang, Yuanjin Lu, Chaobo Liang, Jie Kong, Lixin Chen* and Ju
keywords：EMI
source：期刊
specific source：Composites Part A: Applied Science and Manufacturing, 2019, 123: 293-300.
Issue time：2019年
Few-layered Ti3C2Tx MXene was prepared by ionic intercalation and sonication-assisted method. Porous threedimensional
(3D) Ti3C2Tx MXene/C hybrid foam (MCF) was fabricated by sol-gel followed by thermal reduction.
The MCF/epoxy EMI shielding nanocomposites were obtained via vacuum-assisted impregnation followed by
curing process. When the mass fraction of MCF was 4.25 wt% (MCF-5), the MCF-5/epoxy EMI shielding nanocomposites
exhibited the optimal electrical conductivity of 184 S/m and the maximum EMI SE of 46 dB,
3.1×104 and 4.8 times higher than that of MCF-0/epoxy nanocomposites (without Ti3C2Tx MXene), respectively.
Furthermore, the corresponding Young's modulus of 3.96 GPa and hardness of 0.31 GPa was increased by
13% and 11%, respectively. Conductive networks can realize the attenuation and dissipation of electromagnetic
waves by multiple reflection & reabsorption, and absorption is main shielding mechanism. Unique 3D conductive
networks of MCF would expand wider application of the Ti3C2Tx MXene/polymer-based nanocomposites
in high-tech EMI shielding fields.