Preparation of polymeric sheet porphyrin complexes and their environmentally benignly catalytic activity
writer：Yu-Feng He , Rong-Min Wang ,Yun-Pu Wang , Chun-Gu Xia
keywords：Polymeric sheet porphyrin; Dioxygen; Environmental benign
source：期刊
specific source：Elsevier Science
Issue time：2002年
The polymeric meso-tetra-(1,5-naphthalene bisulfonyloxo)phenylporphyrin and its complexes (PTNBSOPPM,M =Co, Mn, Fe) have been prepared in the presence of phase-transfer catalyst. Catalyzed by polymeric porphyrin
complexes (PTNBSOPPM), styrene can be aerobic oxidized. The main products come from cleavage of double bond is
in catalytic oxidation of styrene or a-methyl styrene.