Preparation of Copolymer of Salen-crown Ether Complexes and its Catalytic Activation for Molecular Oxygen
writer：Rong Min WANG, Xiao Dong LI, Yu Feng HE
keywords：Copolymeric complexes, cyclohexene, catalysis, salen Schiff base, crown ether.ckwave-fla
source：期刊
specific source：Chinese Chemical Letters Vol. 17, No. 2, pp 265-268, 2006
Issue time：2006年
A new stable salen Schiff base cobalt and crown ether sodium complex
(SalCo-NaB18C6) was prepared through copolymerization. This copolymer complex was applied to catalytic oxidation of hydrocarbon compound with molecular oxygen without reductant, which was shown the higher activity and selectivity for ketone, and reused effectively.