Preparation of Copolymer of Salen-crown Ether Complexes and its Catalytic Activation for Molecular Oxygen
作者:Rong Min WANG, Xiao Dong LI, Yu Feng HE
關(guān)鍵字:Copolymeric complexes, cyclohexene, catalysis, salen Schiff base, crown ether.ckwave-fla
論文來(lái)源:期刊
具體來(lái)源:Chinese Chemical Letters Vol. 17, No. 2, pp 265-268, 2006
發(fā)表時(shí)間:2006年
A new stable salen Schiff base cobalt and crown ether sodium complex
(SalCo-NaB18C6) was prepared through copolymerization. This copolymer complex was applied to catalytic oxidation of hydrocarbon compound with molecular oxygen without reductant, which was shown the higher activity and selectivity for ketone, and reused effectively.