119.Self-Assembly of Achiral Shape Amphiphiles into Multi-Walled Nanotubes via Helicity-Selective Nucleation and Growth
作者：Li-Jun Ren, Han Wu, Min-Biao Hu, Yu-Han Wei, Yue Lin,* and Wei Wang*
關鍵字：amphiphiles, helicity, nanotubes · nucleationgrowth process, self-assembly
論文來源：期刊
發(fā)表時間：2018年
Soft nanotubes are normally constructed from chiral amphiphiles through helical self-assembly. Yet, how to self-assemble achiral molecules into nanotubes is still a
challenge. Here, we report the nanotube construction with achiral shape amphiphiles through helical self-assembly and also unravel the formation mechanisms. The amphiphiles
have a dumbbell shape and are composed by covalently linking three achiral moieties together: two unlike clusters and an organic tether. The difference in polarity
between the unlike clusters drives the amphiphiles to self-assemble into single- and multi-walled nanotubes as well as intermediates. Analysis of the key intermediates
unravels the self-assembly mechanism of helicity-selective nucleation and growth. Meanwhile, direct visualization of the individual clusters in the ribbons displays a two-dimensional
deformed hexagonal lattice. Thus, we speculate that it is the lattice deformation that creates anisotropic tension along different directions of the ribbon which further results in the formation of helical ribbons towards nanotubes by amphiphiles.