国内精品国产三级国产在线专_欧美日韩在线播放一区二区_成人xxxx视频_欧美激情视频一区_色女人综合av_久久久亚洲影院_久久久久久九九_成人免费网站在线_日韩美女毛茸茸_狠狠干一区二区

Links
Contact Info.
  • Address:南大仙林化學樓,南京仙林大道163號
  • Zip:210023
  • Tel:025-89686667
  • Fax:
  • Email:[email protected]
Current Location :> Home > Publications > Text
What’s Wrong in the Thermodynamic Theory of Glass Transition?
writer:
keywords:

Current textbooks of polymer physics commonly introduce the thermodynamic theory of glass transition, which describes the glass transition as a second2order phase transition. However ,people have generally accepted the point of view that the nature of glass transition is a kinetic process. We discussed the origin of the thermodynamic theory of glass transition and tried to figure out the false assumptions employed in this theory. First ,we pointed out that the famous Kauzmann paradox may not be a real paradox. Second ,we told the reader that the so2called entropy catastrophe in the result of Floryps lattice statistics of semiflexible polymer solutions may rest on a misinterpretation of the configurational entropy ,and the latter actually means free energy. Therefore ,combining the above paradox with the above catastrophe into the basic assumptions of the thermodynamic theory of glass transition may lead to an illusive result.