Structuring Water Transport Pathway of Chitosan/Poly(vinyl alcohol) Hydrogels towards Achieving High-Efficiency and Salt-Resistive Solar Desalination
作者：Yuankun Wang, Feng Wang, Yu Lu, Defeng Wu*
關鍵字：anisotropic hydrogel; chitosan; water transport pathway; Marangoni effect; desalination.
論文來源：期刊
具體來源：Carbohydrate Polymers
發表時間：2026年
Carbohydrate Polymers, 2026, 379, 125035.
Hydration of polymer networks and hierarchical water transport pathways are crucial for hydrogels as solar evaporators, which require ingenious design from the molecular interactions and pore structures inside the hydrogels to the outside surface architectures. Herein, an anisotropic chitosan (CS)/polyvinyl alcohol (PVA) hydrogel was fabricated by combining the Hofmeister effect and directional freezing ways. Four types of water transport pathways were structured: vertically spaced holes (1 mm) and vessels (20-30 μm) in the top part, accompanied by smaller pores (5-10 μm) inside the hole walls, and the channels (20-100 μm) with bimodal size distributions in the bottom part. The vessel-radially around-hole surface pattern could be molded simultaneously, and the hydration ability was easily tunable by changing CS contents. The optimized hydrogel possessed good thermal insulation (0.30 W m-1 K-1) and excellent light absorption (>97%), and the vaporization enthalpy was only 787 J g-1. Thus, the as-fabricated evaporator showed a desirable performance with 4.51 kg m-2 h-1 evaporation rate and 98.6% energy efficiency (1-sun irradiation). A stable rate (3.02 kg m-2 h-1) could be well maintained over 100 h in the concentrated brine. This work also proposes an integrated strategy of structuring multidirectional pores and regulating water states of PVA hydrogel by using CS-phosphoric acid as precursor.
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https://www.sciencedirect.com/science/article/abs/pii/S0144861726001517