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(JPS Part A) Side-On Main-Chain Liquid Crystalline Polymers Prepared by Acyclic Diene Metathesis Polymerization and Thiol-Ene Click Step-Growth Polymerization
writer:Yang, H.*; Lv, Y.; Lin, B.; Zhang, X.; Sun, Y.; Guo, L.
keywords:LCP
source:期刊
specific source:Journal of Polymer Science, Part A: Polymer Chemistry, 2014, 52, 1086-1098.
Issue time:2014年

In this manuscript, we design and synthesize a series of X-shaped mesogenic monomers, bearing two terminal-alkene tails. Starting from these X-shaped monomers, acyclic diene metathesis polymerization and thiol-ene polyaddition are applied for the first time to prepare two series of side-on main-chain liquid crystalline polymers respectively.