Comparative study on the flame retarded efficiency of melamine phosphate, melamine phosphite and melamine hypophosphite on poly(butylene succinate) composites
作者：Hongyu Yang, Lei Song*, Qilong Tai, Xin Wang, Bin Yu, Yao Yuan, Yuan Hu*, Richard K. K. Yuen
關鍵字：Phosphorus-containing melamine salts; Phosphorus valency; Poly(butylene succinate); Flame retarded efficiency; Flame-retardant mechanism
論文來源：期刊
具體來源：Polymer Degradation and Stability
發表時間：2014年
The main aim of this work was to investigate the flame retarded efficiency of melamine phosphate (MP), melamine phosphite (MPi) and melaminehypophosphite (MHP) on poly(butylene succinate) (PBS) composites. The flame retardant, thermal degradation and combustion properties of PBS composites were characterized by limiting oxygen index (LOI) test, vertical burning (UL-94) test, thermogravimetric analysis (TGA) and cone calorimeter (Cone), respectively. The LOI results showed that the LOI values followed the sequence of PBS/MP < PBS/MHP < PBS/MPi at the same additive loadings. TGA results indicated that the initial decomposition temperature of PBS composites decreased with the decrease of phosphorus valence state and theincorporation of all three compounds could promote the char formation. Adding these three compounds into PBS matrix can decrease the peak heat release rate (PHRR) obviously from cone calorimeter results. Scanning electron microscopy (SEM) was employed to characterize the morphology and structure of the char residues. The flame-retardant mechanism in gaseous phase and condensed phase were investigated by thermogravimetric analysis/infrared spectrometry (TG-IR) and in situ Fourier transform infrared spectroscopy (in situ FTIR), respectively, and the possible flame-retardant mechanism was proposed. (C) 2014 Elsevier Ltd. All rights reserved.