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[Chem. Commun.] Nucleic Acid-Mediated Gold Oxidation: Novel Biolithography for Surface Microfabrication and New Insight on Gold-Based Biomaterials
writer:Peng Yang,* Xu Zhang.
keywords:Nucleic Acid Gold Lithography
source:期刊
specific source:Chemical Communications
Issue time:2012年
In Nature, certain organisms can perform microbial corrosion on base metals by oxidation of neutral metallic atoms (H. L. Ehrlich, Appl. Microbiol. Biotechnol., 1997). Herein we describe the first discovery of biological nucleic acids able to catalyze and mediate gold oxidation from neutral Au(0) to trivalent Au(iii) under certain oxidative environments provided by mild oxidizing reagent N-bromosuccinimide or amino acids. A new biolithography technique for gold patterning is further developed.