Hybrid Nanorattles of Metal Core and Stimuli-Responsive Polymer Shell for Confined Catalytic Reactions
writer：Guoliang Li, Chin An Tai, Koon-Gee Neoh, En-Tang Kang*, Xinlin Yang
keywords：Stimuli-repsonsive microspheres; Multi-layer microsphere
source：期刊
specific source：Polym. Chem., 2 (5), 1368-1374 (2011). DOI: 10.1039/c1py00054c
Issue time：2011年
Narrowly-dispersed
silver@silica@poly(methacrylic acid) (
Ag@SiO2@PMAA) core–double shell hybrid nanoparticles (NPs) were first synthesized by distillation–precipitation polymerization, using
silver@silica core–shell NPs from the sol–gel reaction as templates. Selective removal of the inorganic silica inner-shell from the
Ag@SiO2@PMAA core–double shell hybrid NPs by HF etching produces the
Ag@air@PMAA hybrid nanorattles with a Ag nanocore, PMAA shell and free space in between. The Ag nanocores,
Ag@SiO2 core–shell NPs,
Ag@SiO2@PMAA core–double shell NPs and
Ag@air@PMAA hybrid nanorattles were characterized by field-emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), Fourier-transform infrared (FT-IR) spectroscopy and energy-dispersive X-ray (EDX) analysis. The as-synthesized
Ag@air@PMAA hybrid nanorattles were explored as a nanoreactor system for confined catalytic reaction. The rate of catalytic reaction can be further regulated by controlling molecule diffusion in and out of the stimuli-responsive PMAA shell through the simple variation of environmental stimuli, such as salt (NaCl) concentration of the medium.