Metallopolymers with transition metals in the side-chain by living and controlled polymerization techniques
writer：Christopher G. Hardy, Jiuyang Zhang, Yi Yan, Lixia Ren, Chuanbing Tang
keywords：Metallopolymer, Organometallic Metallocene, Controlled/living polymerization
source：期刊
specific source：Progress in Polymer Science 39 (2014) 1742–1796
Issue time：2014年
Work on side-chain transition metal-containing polymers prepared by controlled and living polymerizations is summarized, including living anionic polymerization (LAP), ringopening metathesis polymerization (ROMP) and controlled radical polymerization (CRP) such as atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer polymerization (RAFT), and nitroxide-mediated polymerization (NMP). These polymers include metallocene-containing polymers, ferrocenylsilane polymers with additional metal at the side chain, metal carbonyl complex polymers, and ligated metal complex polymers.