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Cross-linked polyvinyl alcohol (PVA) composite films with high structural stability were prepared by free radical copolymerization between cellulose nanocrystal (CNC) and maleic anhydride (MAH) modified PVA through spraying Fenton free radical as initiator. The influence of chemical cross-linked and physical network structure on mechanical, thermal and water absorption properties of the composite films were investigated. Compared to PVA and PVA/CNC composite film, significant improvements in the mechanical, therma and water uptake properties of the cross-linked composite film were found. The tensile strength of the cross-linked composite film was enhanced from 23.1 MPa (neat PVA film) and 32.6 MPa (PVA/CNC-10%) to 42.5 MPa, and the maximum thermal degradation temperature was increased from 266.8^oC and 281.2^oC to 366.7^oC (cross-linked composite film). Besides, the water absorption was reduced from 385.9% and 220.6% to 175.7% for cross-linked composite film. It indicates that compared with physical network structure in PVA/CNC composite film, the multiple cross-linked networks showed excellent thermal stability, resistance of water swelling and structural stability at the same CNC loading level. Thus, the PVA/CNC composite film with the multiple cross-linked network shows greater property reinforcements.