[Chem. Res. Chin. Univ.] Functionalized Polyphosphoester via Living Ring-opening Polymerization and Photochemical Thiol-ene Click Reaction
writer：Wang Ying; Wang Qiliao; Hou Liman; Zhou Mingdong; Dong Dewen; Zhang Ning
keywords：Click Reaction，Polyphosphoester，Ring-opening Polymerization
source：期刊
specific source：Chem. Res. Chin. Univ.
Issue time：2019年
Poly(ethylene phosphonate) was synthesized via the living ring-opening polymerization of cyclic phosphonate monomer catalyzed by organocatalyst. The pendant vinyl functionalities were employed to perform the photochemical click reactions with thiols. We demonstrated that both small thiol molecules and macromolecular thiols could be efficiently coupled into the PPE side chains, enabling the rapid and efficient functionalization of polyphosphoesters( PPE).