[J. Am. Chem. Soc.] Surface-Initiated Group Transfer Polymerization (SI-GTP) Mediated by Rare Earth Metal Catalysts
writer：Ning Zhang, Stephan Salzinger, Frank Deubel, Rainer Jordan, and Bernhard Rieger
keywords：group transfer polymerization, rare earth metal, polymer brushes
source：期刊
specific source：JACS
Issue time：2012年
We present the first example of a surfaceinitiated group transfer polymerization (SI-GTP) mediated by rare earth metal catalysts for polymer brush synthesis. The experimentally facile method allows rapid grafting of polymer brushes with a thickness of >150 nm in <5 min at room temperature. We show the preparation of common
poly(methacrylate) brushes and demonstrate that SI-GTP is a versatile route for the preparation of novel polymer brushes. The method gives access to both thermoresponsive and proton-conducting brush layers.
http://pubs.acs.org/doi/abs/10.1021/ja3027423?mi=uvozc9&af=R&pageSize=20&searchText=peptide