国内精品国产三级国产在线专_欧美日韩在线播放一区二区_成人xxxx视频_欧美激情视频一区_色女人综合av_久久久亚洲影院_久久久久久九九_成人免费网站在线_日韩美女毛茸茸_狠狠干一区二区

pubs.acs.org/doi/abs/10.1021/ma0509199

Thermoresponsive micellization of poly(ethylene glycol)-b-poly(N-isopropylacrylamide) (PEG110-b-PNIPAM44) in water is studied by static light scattering and dynamic light scattering. The critical aggregation temperature of PEG110-b-PNIPAM44 is a little higher than homopolymer PNIPAM, and it depends on the block copolymer concentration, which increases from 33.7 to 38.4°C when the copolymer concentration decreases from 2.0 to 0.20 mg/mL. Above the critical aggregation temperature, thermoresponsive micellization occurs, and the resultant spherical micelles consist of a PNIPAM core and a PEG shell. The block copolymer concentration exerts a strong influence on the size and structure of the resultant micelles. Micellization of PEG110-b-PNIPAM44 at higher copolymer concentration favors formation of narrowly distributed, small, and dense micelles, while large, loose micelles or micellar clusters form at lower block copolymer concentration.