Photoswitchable and Reversible Fluorescent Eutectogels for Conformal Information Encryption
writer：Changchun Li, Jize Liu, Xiaoyan Qiu, Xin Yang, Xin Huang, Prof. Xinxing Zhang
keywords：supramolecular interactions, eutectogels,photoswitchable fluorescence, conformally deform
source：期刊
specific source：Angewandte Chemie
Issue time：2023年
Smart fluorescent materials that can respond to environmental stimuli are of great importance in the fields of information encryption and anti-counterfeiting. However, traditional fluorescent materials usually face problems such as lack of tunable fluorescence and insufficient surface-adaptive adhesion, hindering their practical applications. Herein, inspired by the glowing sucker octopus, we present a novel strategy to fabricate a reversible fluorescent eutectogel with high transparency, adhesive and self-healing performance for conformal information encryption and anti-counterfeiting. Using anthracene as luminescent unit, the eutectogel exhibits photoswitchable fluorescence and can therefore be reversibly written/erased with patterns by non-contact stimulation. Additionally, different from mechanically irreversible adhesion via glue, the eutectogel can adhere to various irregular substrates over a wide temperature range (?20 to 65?°C) and conformally deform more than 1000?times without peeling off. Furthermore, by exploiting surface-adaptive adhesion, high transparency and good stretchability of the eutectogel, dual encryption can be achieved under UV and stretching conditions to further improve the security level. This study should provide a promising strategy for the future development of advanced intelligent anti-counterfeiting materials.