Facile synthesis and versatile topological transformation of mono-cleavable symmetric starlike terpolymers
writer：Xiao Jiang, Meijing Zhang, Shixian Li, Wei Shao, Youliang Zhao*
keywords：RAFT, miktoarm stars, biocleavable
source：期刊
specific source：Chem. Commun
Issue time：2012年
http://pubs.rsc.org/en/content/articlelanding/2012/cc/c2cc35275c
A straightforward strategy involving a RAFT process and ring-opening polymerization was used to construct symmetric reduction-responsive amphiphilic A2mB2nC2 (m ≈ n ≈ 3) starlike terpolymers with precise microstructure, which could be efficiently converted into thiol-functionalized telechelic stars, degraded AmBnC miktoarm stars and comblike-linear multiblock copolymers via postmodification.