Reversible addition-fragmentation chain transfer (RAFT) polymerization from surfaces
writer：Youliang Zhao,* Sébastien Perrier
keywords：RAFT, surface modification
source：期刊
specific source：Adv. Polym. Sci., 2016, 270, 77–106 (DOI: 10.1007/12_2015_316)
Issue time：2016年
Reversible addition–fragmentation
chain transfer (RAFT) polymerization based surface modification has emerged as
a powerful tool for preparation of well-defined polymers grafted solid
substrates. Combination of the RAFT process with highly efficient ligation
reactions involving click chemistry can further extend its application in
controlled synthesis of functional hybrid and composite materials. This review
highlights some basic features of this method and describes synthesis of polymer-grafted
solid surfaces such as silica particles,metal oxide, gold nanoparticles, cellulose,
and graphene oxide. Applications of such functional materials, including their
use in functional additives, bioactive surfaces and biomaterials, stationary
phases for chromatographic applications, and preparation of hollowcapsules and
molecularly imprinted polymer films, are also summarized.