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Direct Microscopic Observation of Shish-Kebab Structure in High-temperature Electrospun iPP Fibers
writer:Shuangyang Liu, Feifei Zhang, Guoqiang Zheng(通訊作者), Kun Dai, Chuntai Liu, Changyu Shen, John Zhanhu
keywords:Polymers, Shish-kebab structure, Isotactic polypropylene, Electrospinning, Crystal growth
source:期刊
specific source:Materials Letters, 2016, 172, 149-152
Issue time:2016年
keywords:Polymers, Shish-kebab structure, Isotactic polypropylene, Electrospinning, Crystal growth
source:期刊
specific source:Materials Letters, 2016, 172, 149-152
Issue time:2016年
Electrospinning is not only a technique to fabricate macroscopic fiber but also a method to control the microstructure. In this study, high-temperature solution electrospinning was used to prepare isotactic polypropylene (iPP) fibers. Scanning electron microscope (SEM) observation indicates that a single electrospun iPP fiber consists of many nano-fibrils. Based on SEM observation, these nano-fibrils are shish-kebab structure. Electrostatic elongational force involved in the electrospinning process is considered to be responsible for the development of shish-kebab structure.