Enhancing efficiency and stability of perovskite solar cells via in situ incorporation of lead sulfide layer
writer：Yue Zhang, Yuxia Han, Yanting Xu, Guanghui Yu, Yu Miao, CaiYan Gao, Xueqin Zhou, YanLin Song, Ke-Jia
keywords：perovskite solar cells, in situ incorporation
source：期刊
specific source：Sustainable Energy Fuels
Issue time：2021年
The trap states at the surface and grain boundaries of perovskite films have a great influence on the photovoltaic performance and stability of perovskite solar cells (PSCs). Herein, lead sulfide (PbS) was introduced on the surface of perovskite films through in situ reaction with thioacetamide (TAA) in solution. With the PbS layer, the trap state density of the perovskite film was significantly reduced, and charge extraction efficiency was enhanced from perovskite to the external charge transport layer. In addition, it was found that the water-insoluble PbS layer could effectively protect the perovskite film from the moisture permeation. As a result, the perovskite solar cell exhibited a stable output efficiency of 22.04% with high stability.