A Supramolecular Janus Hyperbranched Polymer and Its Photoresponsive Self-Assembly of Vesicles with Narrow Size Distribution
writer：Liu, Y.; Yu, C. Y.; Jin, H. B.; Jiang, B. B.; Zhu, X. Y.; Zhou, Y. F.*; Lu, Z. Y.*; Yan, D. Y.
keywords：Supramolecular Janus Hyperbranched Polymer, Self-Assembly
source：期刊
specific source：J. Am. Chem. Soc. 2013, 135, 4765. http://pubs.acs.org/doi/pdf/10.1021/ja3122608
Issue time：2013年
Herein, we report a novel Janus
particle and supramolecular block copolymer consisting of two chemically
distinct hyperbranched polymers, which is coined as Janus hyperbranched polymer.
It is constructed by the noncovalent coupling between a hydrophobic
hyperbranched poly(3-ethyl-3-oxetanemethanol) with an apex of an azobenzene
(AZO) group and a hydrophilic hyperbranched polyglycerol with an apex of a
β-cyclodextrin (CD) group through the specific AZO/CD host–guest interactions.
Such an amphiphilic supramolecular polymer resembles a tree together with its
root very well in the architecture and can further self-assemble into
unilamellar bilayer vesicles with narrow size distribution, which disassembles
reversibly under the irradiation of UV light due to the trans-to-cis isomerization of the AZO groups. In addition, the
obtained vesicles could further aggregate into colloidal crystal-like
close-packed arrays under freeze-drying conditions. The dynamics and mechanism
for the self-assembly of vesicles as well as the bilayer structure have been
disclosed by a dissipative particle dynamics simulation.