writer：Xin Lia, Yongbing Zhuang, Qichao Ran and Xiangyang Liu
keywords：Oxidative evolution, diaminotetraphenylethylene
source：期刊
specific source：Phys. Chem. Chem. Phys, 2022, DOI: 10.1039/d1cp05303e
Issue time：2022年
We report that Z/E-diaminotetraphenylethylene (Z/E-2NH2-TPE) molecules suffer primarily from oxidative evolution rather than recognized isomerization. The oxide is separated and its structure is deciphered by single crystal X-ray diffraction. The oxidative evolution
accompanying the rearrangement is explained through quantum theoretical calculation.