Tailored Parallel Graphene Stripes in Plastic Film with Conductive Anisotropy by Shear-Induced Self-Assembly
writer：Cui Mao,Jinrui Huang,Yutian Zhu,*Wei Jiang,*Qingxin Tang,and Xiaojing Ma
keywords：Graphene Stripes;Conductive Anisotropy;Shear-Induced Self-Assembly
source：期刊
Issue time：2013年
We present a simple but efficient route to prepare a highly anisotropic conductive plastic thin film from the polypropylene/(styrene-ethylene/butadiene-styrene) triblock copolymer/graphene blend via shear-induced self-assembly. Under the shear-flow induction, GE nanosheets dispersed in the polymer matrix can spontaneously assemble into ordered parallel stripes, which endow the materials significantly conductive anisotropy. The electrical resistivity in the direction parallel to the graphene stripes is almost four orders of magnitude lower than that which is perpendicular to the stripes. This study provides a new method for the precise control of the organization of functional nano-objects in polymer matrix, which can be widely extended to the fabrication of other multifunctional anisotropic materials of interest in various fields.