Fabrication of exfoliated graphene-based polypropylene nanocomposites with enhanced mechanical and thermal properties
writer：Song PA, Cao ZH, Cai YZ, Zhao LP, Fang ZP*, Fu SY*
keywords：Graphene; Polypropylene; Mechanical properties, Thermal properties
source：期刊
specific source：Polymer, 2011.7, 52: 4001-4010
Issue time：2011年
Despite the great potential of graphene as the nanofiller, to achieve homogeneous dispersion remains the key challenge for effectively reinforcing the polymer. Here, we report an eco-friendly strategy for fabricating the polymer nanocomposites with well-dispersed graphene sheets in the polymer matrix via first coating graphene using polypropylene (PP) latex and then melt-blending the coated graphene with PP matrix. A ~75% increase in yield strength and a ~74% increase in the Young’s modulus of PP are achieved by addition of only 0.42 vol% of graphene due to the effective external load transfer. The glass transition temperature of PP is enhanced by ~2.5 oC by incorporating only 0.041 vol% graphene. The thermal oxidative stability of PP is also remarkably improved with the addition of graphene, for example, compared with neat PP, the initial degradation temperature is enhanced by 26 oC at only 0.42 vol% of graphene loading.