[Macromol. Rapid Commun.] A Color-Tunable Fluorescent Supramolecular Hyperbranched Polymer Constructed by Pillar[5]arene-Based Host–Guest Recognition and Metal Ion Coordination Interaction
writer：Hui Li, Wenzhuo Chen, Fenfen Xu, Xiaodong Fan, Tongxiang Liang,* Xiaopeng Qi, and Wei Tian*
keywords：fluorescent supramolecular hyperbranched polymers, host–guest interactions, metal coordination
source：期刊
specific source：Macromol. Rapid Commun. 2018, 1800053
Issue time：2018年
Fluorescent supramolecular polymers are an important kind of smart material. In this work, a new fluorescent supramolecular hyperbranched polymer (FSHP) is constructed by orthogonal self-assembly: pillararene-based host–guest interaction and metal ion complexation interaction. The FSHP exhibits concentration-controllable fluorescence emissions. The photoluminescence spectra and light-emitting colors of FSHP can be effectively tuned by changing metal ion types or using mixed metal ions. The fluorescence quenching of FSHP solutions or FSHP-based films would occur when removing the metal ions from the backbone of FSHP. This study supplies a convenient approach toward the construction of structure-tunable fluorescent supramolecular materials with different colors.
全文鏈接：
https://onlinelibrary.wiley.com/doi/abs/10.1002/marc.201800053