[Macromolecular Materials & Engineering]Highly Flexible, Tough, and Self-Healable Hydrogels Enabled by Dual Cross-Linking of Triblock Copolymer Micelles and Ionic Interactions
作者：H. W. Zhou,* M. Zhang, J. C. Cao, B. Yan, W. Yang, X. L. Jin, A. J. Ma, W. X. Chen, X. B. Ding, G. Z
關鍵字：hydrogel, ionic interaction, micelle ,self‐healing ,tough
論文來源：期刊
具體來源：Macromolecular Materials & Engineering
發表時間：2017年
Development of artificial soft materials that have good mechanical performances and autonomous healing ability is a longstanding pursuit but remains challenging. This work reports a kind of highly flexible, tough, and self-healable poly(acrylic acid)/Fe(III) (PAA/Fe(III)) hydrogels. The hydrogels are dually cross-linked by triblock copolymer micelles and ionic interaction between Fe(III) and carboxyl groups. Due to the coexistence of these two cross-linking points, the resulting PAA/Fe(III) hydrogels are tough and can be flexibly stretched, bent, knotted, and twisted. The hydrogels can withstand a deformation of 600% and an ultimate stress as high as 250 kPa. Moreover, the dynamic ionic interaction also endows the hydrogels self-healing properties. By varying the ratio of Fe(III)/AA, a compromised healing efficiency of 73% and an ultimate stress of 200 kPa are obtained